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- W1982123630 abstract "Development of nitrite-selective bulk optode membranes, based on novel organopalladium ionophores, is described herein. These nitrite-selective optodes are composed of a plasticized poly(vinyl chloride) impregnated with the organopalladium ionophore, a proton-selective chromoionophore, and in some cases lipophilic additives. Two novel organopalladium ionophores (NI-I and NI-II) and different proton chromoionophores (ETH-7075, ETH-5294 and ETH-2439) were evaluated for the development of nitrite-selective bulk optode membranes. The developed nitrite optodes were found to be more selective for nitrite over other anions including the more lipophilic anions such as perchlorate, nitrate, iodide, and bromide. For instance, the optical selectivity coefficients, log K nitrite, anion opt, for NI-I, ETH-7075 optode are as follow: ClO4 −, −1.2; NO3 −, −3.4; I−, −1.5; Br−, −2.1. Further, the nitrite optical selectivity obtained using the present optode systems is greatly enhanced in comparison with that obtained using..." @default.
- W1982123630 created "2016-06-24" @default.
- W1982123630 creator A5066689153 @default.
- W1982123630 date "2001-08-31" @default.
- W1982123630 modified "2023-09-26" @default.
- W1982123630 title "NITRITE-SELECTIVE OPTICAL SENSORS BASED ON ORGANOPALLADIUM IONOPHORES" @default.
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- W1982123630 doi "https://doi.org/10.1081/al-100106836" @default.
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