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- W1982128081 abstract "1H and 13C NMR data indicate the presence of N-aryl substituted phthalic imidines to exist as 3-amino-1-N-arylimino-1H-isoindole compounds in DMSO-d6. In CDCl3 a tautomeric equilibrium mixture containing 20% of the imino form is observed. The presence of a dimeric association through intramolecular H bonds is suggested. It is shown that intramolecular NH-N hydrogen bonds displace the tautomeric equilibrium toward the imino tautomer in 2-pyridyl substituted phthalic imidines. In the reaction product of phthalic imidine and 2, 6-diaminopyridine, 11, two pairs of intramolecular NH-N hydrogen bonds result in the presence of both amino and imino tautomeric forms in the same molecular species." @default.
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- W1982128081 date "2010-09-01" @default.
- W1982128081 modified "2023-09-23" @default.
- W1982128081 title "NMR studies on imidines. VII. The tautomerism of mono-n-aryl substituted phthalic imidines. A 1H and 13C nuclear magnetic resonance study" @default.
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- W1982128081 doi "https://doi.org/10.1002/bscb.19880970604" @default.
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