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- W1982129606 abstract "Abstract CO2 and KrF laser-induced dissociation of dimethyl disulfide opens two major primary dissociation channels. The moleculer elimination channel produces S2 and C2H6 via a four-centered transition state whereas the radical channel generates two CH3S radicals. The time-resolved UV absorption spectra of the transients CH3S and S2 are reported. From the real time formation of CH3S radical, a unimolecular dissociation rate constant for dimethyl disulfide has been found to be 6.8 × 105 s−1 and ⩾ 1 × 107 s−1 in the IR and UV laser photolysis, respectively. In SF6-sensitised dissociation of dimethyl disulfide, a time lag between the laser pulse and the onset of dissociation is observed, which is ascribed to intermolecular energy transfer from vibrationally excited SF6 to the substrate." @default.
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- W1982129606 date "1992-10-01" @default.
- W1982129606 modified "2023-09-22" @default.
- W1982129606 title "Four-centered concerted ethane elimination in the IR and UV laser photolysis of dimethyldisulfide. Real-time observation of S2 and CH3S radicals" @default.
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- W1982129606 doi "https://doi.org/10.1016/0009-2614(92)85073-j" @default.
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