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- W1982132045 abstract "Photochemical grafting of ferrocene to Si was investigated in a vinylferrocene solution in tetrahydrofuran, diethyl ether, or dibutyl ether. The grafting of vinylferrocene onto a Si(111) surface was carried out by placing a hydrogen-terminated Si(111) substrate into a vinylferrocene–solvent solution and illuminating the substrate with visible light. The samples prepared in vinylferrocene–diethyl ether and vinylferrocene–dibutyl ether solutions yielded ferrocene-terminated Si(111) and the oxidation states of Fe were mainly +2. On the other hand, a polymerized vinylferrocene layer was formed on the samples treated in the vinylferrocene–tetrahydrofuran solution and the oxidation states of Fe were +3. In addition, the dibutyl ether-prepared sample showed a cleaner surface than that of the diethyl ether-prepared sample." @default.
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- W1982132045 date "2012-10-05" @default.
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- W1982132045 title "Vinylferrocene Photochemical Preparation on Si(111) Surface in Different Grafting Media" @default.
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- W1982132045 doi "https://doi.org/10.1246/cl.2012.1188" @default.
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