Matches in SemOpenAlex for { <https://semopenalex.org/work/W1982152098> ?p ?o ?g. }
- W1982152098 endingPage "124" @default.
- W1982152098 startingPage "115" @default.
- W1982152098 abstract "Silicone acrylic-urethane/amino-silane coatings are considered as promising candidates for use as a topcoat in high-temperature engineering applications. However, under these conditions, their functional properties can be affected, and it is well known that the loss of functional properties is related to modification of the chemical structure. The main objective of this first study is to identify the main criteria for degradation and establish a mechanism of degradation. For this purpose, the thermo-oxidative ageing of the topcoat is studied at the molecular scale using FTIR coupled with chemical treatments, TGA, and SPME/GC-MS. These complementary techniques allow the study of both the solid and gas phases and provide evidence for a more comprehensive degradation mechanism of this topcoat. The results show that degradation occurs on the labile hydrogen atoms located on the tertiary carbon of the acrylate group and on the α-position of the ester and amide. The solid phase oxidation products were identified as anhydrides and amides, whereas volatile products such as lactones and siloxanes were identified in the gas phase." @default.
- W1982152098 created "2016-06-24" @default.
- W1982152098 creator A5015352026 @default.
- W1982152098 creator A5032423148 @default.
- W1982152098 creator A5051269959 @default.
- W1982152098 creator A5075136999 @default.
- W1982152098 creator A5077392712 @default.
- W1982152098 creator A5079022214 @default.
- W1982152098 date "2015-04-01" @default.
- W1982152098 modified "2023-09-30" @default.
- W1982152098 title "Investigation of the thermo-oxidation mechanism of acrylic-urethane-silicone/amino-silane based topcoat" @default.
- W1982152098 cites W1965161556 @default.
- W1982152098 cites W1966993500 @default.
- W1982152098 cites W1967702200 @default.
- W1982152098 cites W1969239631 @default.
- W1982152098 cites W1985347125 @default.
- W1982152098 cites W1994117615 @default.
- W1982152098 cites W2002423307 @default.
- W1982152098 cites W2004911827 @default.
- W1982152098 cites W2006779985 @default.
- W1982152098 cites W2007255490 @default.
- W1982152098 cites W2012715685 @default.
- W1982152098 cites W2013426418 @default.
- W1982152098 cites W2014183835 @default.
- W1982152098 cites W2021476242 @default.
- W1982152098 cites W2021879539 @default.
- W1982152098 cites W2023438566 @default.
- W1982152098 cites W2028348785 @default.
- W1982152098 cites W2029155947 @default.
- W1982152098 cites W2034479251 @default.
- W1982152098 cites W2036419609 @default.
- W1982152098 cites W2038075089 @default.
- W1982152098 cites W2041259206 @default.
- W1982152098 cites W2045710858 @default.
- W1982152098 cites W2047572586 @default.
- W1982152098 cites W2050198054 @default.
- W1982152098 cites W2053503539 @default.
- W1982152098 cites W2057774365 @default.
- W1982152098 cites W2058149815 @default.
- W1982152098 cites W2068788398 @default.
- W1982152098 cites W2071390021 @default.
- W1982152098 cites W2073390489 @default.
- W1982152098 cites W2075894226 @default.
- W1982152098 cites W2087138575 @default.
- W1982152098 cites W2090772888 @default.
- W1982152098 cites W2091253665 @default.
- W1982152098 cites W2092941702 @default.
- W1982152098 cites W2093358038 @default.
- W1982152098 cites W2147972582 @default.
- W1982152098 cites W2150409440 @default.
- W1982152098 cites W2166484778 @default.
- W1982152098 cites W2169551606 @default.
- W1982152098 cites W2323086252 @default.
- W1982152098 cites W2373032277 @default.
- W1982152098 cites W2475941090 @default.
- W1982152098 doi "https://doi.org/10.1016/j.polymdegradstab.2014.12.011" @default.
- W1982152098 hasPublicationYear "2015" @default.
- W1982152098 type Work @default.
- W1982152098 sameAs 1982152098 @default.
- W1982152098 citedByCount "9" @default.
- W1982152098 countsByYear W19821520982015 @default.
- W1982152098 countsByYear W19821520982016 @default.
- W1982152098 countsByYear W19821520982018 @default.
- W1982152098 countsByYear W19821520982019 @default.
- W1982152098 countsByYear W19821520982020 @default.
- W1982152098 countsByYear W19821520982022 @default.
- W1982152098 crossrefType "journal-article" @default.
- W1982152098 hasAuthorship W1982152098A5015352026 @default.
- W1982152098 hasAuthorship W1982152098A5032423148 @default.
- W1982152098 hasAuthorship W1982152098A5051269959 @default.
- W1982152098 hasAuthorship W1982152098A5075136999 @default.
- W1982152098 hasAuthorship W1982152098A5077392712 @default.
- W1982152098 hasAuthorship W1982152098A5079022214 @default.
- W1982152098 hasConcept C127413603 @default.
- W1982152098 hasConcept C153642686 @default.
- W1982152098 hasConcept C159985019 @default.
- W1982152098 hasConcept C160892712 @default.
- W1982152098 hasConcept C166940927 @default.
- W1982152098 hasConcept C175528265 @default.
- W1982152098 hasConcept C178790620 @default.
- W1982152098 hasConcept C185592680 @default.
- W1982152098 hasConcept C188027245 @default.
- W1982152098 hasConcept C192562407 @default.
- W1982152098 hasConcept C2778024649 @default.
- W1982152098 hasConcept C2778439535 @default.
- W1982152098 hasConcept C2779679103 @default.
- W1982152098 hasConcept C2779769944 @default.
- W1982152098 hasConcept C2779989194 @default.
- W1982152098 hasConcept C41008148 @default.
- W1982152098 hasConcept C42360764 @default.
- W1982152098 hasConcept C521977710 @default.
- W1982152098 hasConcept C533411734 @default.
- W1982152098 hasConcept C76155785 @default.
- W1982152098 hasConceptScore W1982152098C127413603 @default.
- W1982152098 hasConceptScore W1982152098C153642686 @default.
- W1982152098 hasConceptScore W1982152098C159985019 @default.
- W1982152098 hasConceptScore W1982152098C160892712 @default.
- W1982152098 hasConceptScore W1982152098C166940927 @default.