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- W1982183433 abstract "Abstract. Silica scales containing large amounts of smectite were recently found in the pipelines for geothermal water at a geothermal power plant. To elucidate the mechanism of smectite formation, seven silica scale samples were characterized by powder X-ray diffraction, chemical analysis and 27A1 MAS NMR. Smectite was present in samples with MgO levels above 10 wt% and Al2O3 levels below 10 wt%. In 27A1 MAS NMR spectra, peaks assigned to both tetrahedrally and octahedrally coordinated aluminum (Al(4) and Al(6)) were observed for Mg-rich samples, whereas a peak due to Al(4) alone appeared in Mg-poor samples. From these observation and comparison between 27A1 MAS NMR spectra for synthesized precipitates of Al2O3-SiO2 containing MgO and not containing MgO, it is concluded that magnesium plays an important role in the stabilization of Al(6), and results in the formation of smectite" @default.
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- W1982183433 date "2005-09-01" @default.
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- W1982183433 title "A Study on the Formation of Smectite in Silica Scales Precipitated from Geothermal Water: The Effect of Magnesium" @default.
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- W1982183433 doi "https://doi.org/10.1111/j.1751-3928.2005.tb00248.x" @default.
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