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• W1982184018 endingPage "1609" @default.
• W1982184018 startingPage "1602" @default.
• W1982184018 abstract "A combination of picosecond photoluminescence and electrochemical studies reveals information about the GaAs/methanol interface. The electrochemistry occurring at the solid/nonaqueous liquid junction is found to have a strong influence on the observed photoluminescence as seen by photoluminescence vs voltage (PL−V) scans and by trends in the time-resolved photoluminescence decays. The effect of corrosion of the cell on the PL−V profile is examined in detail. It is found that the inclusion of the redox couple gives some protection from corrosion, but the addition of a small amount of water to the nonaqueous cell gives even more. Further water additions lead the cell back to a state that is conducive to corrosion and eventually leads to Fermi level pinning of the GaAs." @default.
• W1982184018 created "2016-06-24" @default.
• W1982184018 creator A5031218150 @default.
• W1982184018 creator A5048017733 @default.
• W1982184018 date "2000-01-27" @default.
• W1982184018 modified "2023-09-26" @default.
• W1982184018 title "Corrosion, Passivation, and the Effect of Water Addition on an n-GaAs(100)/Methanol Photoelectrochemical Cell" @default.
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• W1982184018 doi "https://doi.org/10.1021/jp993782v" @default.
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