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- W1982185612 abstract "Es wird ein verbessertes Darstellungsverfahren für Rubidiumozonid mitgeteilt, das über die Ozonisierung des Hyperoxides bei Raumtemperatur und anschließende Anreicherung durch Extraktion mit flüssigem Ammoniak erstmals RbO3 in einkristalliner Form und in präparativen Mengen (1–5 g) zugänglich macht. Die Röntgenstrukturanalyse (P21/c; a = 645,2(3), b = 602,2(3), c = 876,3(3) pm, ß = 122,34(2)°; −20°C; MoKα; 2640 Diffraktometerdaten; Rw = 2,6%) sichert die vermutete Konstitution des Anions O3−, das innerhalb der Fehlergrenzen die Punktsymmetrie C2v aufweist mit d(OO) = 133,6(9) pm und einem Bindungswinkel von 113,7(7)°. Hinsichtlich der Packung von Kationen und Anionen besteht eine enge Beziehung zur CsCl-Struktur. On Rubidium Ozonide. Synthesis and Crystal Structure An improved route for the synthesis of rubidium ozonide is reported. Via repeated ozonization of the hyperoxide at room temperature and extraction with liquid ammonia, pure rubidium ozonide is for the first time available in preparative amounts (1–5 g) and moreover as single crystals. The crystal structure determination (P21/c; a = 645.2(3), b = 602.2(3), c = 876.3(3) pm, ß 122.34(2)°; −20°C; MoKα 2640 diffractometer data; Rw = 2.6%) proves the expected constitution of the anion O3−, which within the range of error belongs to the point group C2v with d(OO) = 133.6(9) pm and a bonding angle of 113.7(7)°. With respect to the packing of cations and anions there is a close relationship to the CsCl-type of structure." @default.
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- W1982185612 date "1986-01-01" @default.
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- W1982185612 title "�ber Rubidiumozonid. Reindarstellung und Kristallstruktur" @default.
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- W1982185612 doi "https://doi.org/10.1002/zaac.19865320107" @default.
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