Matches in SemOpenAlex for { <https://semopenalex.org/work/W1982186415> ?p ?o ?g. }
- W1982186415 abstract "The emission lifetime of bis(1,1,1,5,5,5-hexafluoro-2,4-pentanedionato)(teterahydrofuran)dioxouranium(VI) complex, UO 2 (hfac) 2 thf, has been measured in sub and supercritical carbon dioxide (sc-CO 2 ) under the conditions of 10 to 60MPa and 293.2 to 340.2 K. It was found that the decay rate constants of excited UO 2 (hfac) 2 thf species (*UO 2 (hfac) 2 thf) decrease with increasing the pressure of sc-CO 2 . The rate constants for quenching reactions of *UO 2 (hfac) 2 thf with alkenes in sc-CO 2 were determined as 4.32 × 109(for cyclohexene), 3.04 × 109(for cycloheptene), 2.13 × 10 9 (for 1-octene), and 3.81 x 10 8 mol -1 .dm 3 .s -1 (for 1-hexene). The activation volumes for the quenching reactions of *UO 2 (hfac) 2 thf with cyclohexene, cycloheptene, 1-octene, and 1-hexene at 308.2 K were determined to be 16.7, 28.7, 16.7, and 24.7 cm 3 .mol -1 , respectively." @default.
- W1982186415 created "2016-06-24" @default.
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- W1982186415 date "2003-06-01" @default.
- W1982186415 modified "2023-10-18" @default.
- W1982186415 title "Photochemical Reaction of Bis(1,1,1,5,5,5-hexafluoro-2,4-pentanedionato) (tetrahydrofuran)dioxouranium(VI) in Supercritical Carbon Dioxide" @default.
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- W1982186415 doi "https://doi.org/10.1080/18811248.2003.9715372" @default.
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