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- W1982191036 abstract "Accurate molecular constants for the low vibrational levels of the A2Σ+ and X2Πi states of OD are reported for the first time. All available literature data are analyzed by the direct two-state fit approach. The problem of almost total correlation between the first-order spin-rotation coupling constant (γ) and the second-order centrifugal spin-orbit constant (AD = 2AJ) in 2Π states is discussed in detail. A new general procedure for the calculation of AD is described and gives results similar to the approximation proposed by Veseth. The molecular constants of OD are used to compute RKR potential energy curves and a set of J-dependent Franck-Condon factors for v′ ≤ 3, v″ ≤ 3 of the A2Σ+-X2Πi system." @default.
- W1982191036 created "2016-06-24" @default.
- W1982191036 creator A5008824913 @default.
- W1982191036 date "1975-10-01" @default.
- W1982191036 modified "2023-09-23" @default.
- W1982191036 title "The A2Σ+-X2Πi system of OD" @default.
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- W1982191036 doi "https://doi.org/10.1016/0022-2852(75)90153-8" @default.
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