Matches in SemOpenAlex for { <https://semopenalex.org/work/W1982191413> ?p ?o ?g. }
Showing items 1 to 77 of
77
with 100 items per page.
- W1982191413 endingPage "582" @default.
- W1982191413 startingPage "577" @default.
- W1982191413 abstract "Abstract A simple bent M←OL vibrational model has been used to estimate from ν(MO) and ν(SO) the force constants FMO and FOL for some O-bonded DMSO (dimethylsulfoxide), DMSO-d6 and TMSO (tetramethylenesulfoxide) complexes. The correlation FOL = −(1.24 ± 0.2)FMO + (8.78 ± 0.12)mdyne/A holds for all such complexes of the following metals in the oxidation states noted: AlIII, CaII, CrIII, MnII, FeII, FeIII, CoII, NiII, CuII, RuII, RhI, RhIII, PdII, LaIII, NdIII, YbIII, LuIII, PtII, HgII, and is explained by a reduction of oxygen (Pπ) → sulfur (dπ) double-bond character as the MO bond strengthens. The trend is usefully applied to aid the assignment of the i.r. spectra of a series of lanthanide(III)-DMSO complexes. The correlation does not hold for complexes of the group IVA and VA elements SnIV, SbIII, BiIII and BiV." @default.
- W1982191413 created "2016-06-24" @default.
- W1982191413 creator A5014503768 @default.
- W1982191413 creator A5039634682 @default.
- W1982191413 date "1978-01-01" @default.
- W1982191413 modified "2023-10-16" @default.
- W1982191413 title "Vibrational analysis of oxygen-bonded sulfoxide complexes" @default.
- W1982191413 cites W1963658833 @default.
- W1982191413 cites W1972525258 @default.
- W1982191413 cites W1973075728 @default.
- W1982191413 cites W1973357398 @default.
- W1982191413 cites W1975480549 @default.
- W1982191413 cites W1984358164 @default.
- W1982191413 cites W1990581030 @default.
- W1982191413 cites W1991714168 @default.
- W1982191413 cites W2018581678 @default.
- W1982191413 cites W2019908825 @default.
- W1982191413 cites W2026174666 @default.
- W1982191413 cites W2035567389 @default.
- W1982191413 cites W2037838787 @default.
- W1982191413 cites W2056409506 @default.
- W1982191413 cites W2056833222 @default.
- W1982191413 cites W2060945002 @default.
- W1982191413 cites W2063039679 @default.
- W1982191413 cites W2063571165 @default.
- W1982191413 cites W2065476924 @default.
- W1982191413 cites W2067725797 @default.
- W1982191413 cites W2067806827 @default.
- W1982191413 cites W2075621193 @default.
- W1982191413 cites W2076685554 @default.
- W1982191413 cites W2076891055 @default.
- W1982191413 cites W2084704637 @default.
- W1982191413 cites W2113353077 @default.
- W1982191413 cites W2315545491 @default.
- W1982191413 cites W2952038229 @default.
- W1982191413 cites W341882309 @default.
- W1982191413 doi "https://doi.org/10.1016/0584-8539(78)80056-7" @default.
- W1982191413 hasPublicationYear "1978" @default.
- W1982191413 type Work @default.
- W1982191413 sameAs 1982191413 @default.
- W1982191413 citedByCount "22" @default.
- W1982191413 countsByYear W19821914132012 @default.
- W1982191413 countsByYear W19821914132016 @default.
- W1982191413 crossrefType "journal-article" @default.
- W1982191413 hasAuthorship W1982191413A5014503768 @default.
- W1982191413 hasAuthorship W1982191413A5039634682 @default.
- W1982191413 hasConcept C178790620 @default.
- W1982191413 hasConcept C185592680 @default.
- W1982191413 hasConcept C192562407 @default.
- W1982191413 hasConcept C2778448320 @default.
- W1982191413 hasConcept C540031477 @default.
- W1982191413 hasConceptScore W1982191413C178790620 @default.
- W1982191413 hasConceptScore W1982191413C185592680 @default.
- W1982191413 hasConceptScore W1982191413C192562407 @default.
- W1982191413 hasConceptScore W1982191413C2778448320 @default.
- W1982191413 hasConceptScore W1982191413C540031477 @default.
- W1982191413 hasIssue "6" @default.
- W1982191413 hasLocation W19821914131 @default.
- W1982191413 hasOpenAccess W1982191413 @default.
- W1982191413 hasPrimaryLocation W19821914131 @default.
- W1982191413 hasRelatedWork W1968673525 @default.
- W1982191413 hasRelatedWork W2076064914 @default.
- W1982191413 hasRelatedWork W2406084287 @default.
- W1982191413 hasRelatedWork W2899084033 @default.
- W1982191413 hasRelatedWork W2949702109 @default.
- W1982191413 hasRelatedWork W2949977175 @default.
- W1982191413 hasRelatedWork W2951133478 @default.
- W1982191413 hasRelatedWork W2951950061 @default.
- W1982191413 hasRelatedWork W3004506674 @default.
- W1982191413 hasRelatedWork W4285223579 @default.
- W1982191413 hasVolume "34" @default.
- W1982191413 isParatext "false" @default.
- W1982191413 isRetracted "false" @default.
- W1982191413 magId "1982191413" @default.
- W1982191413 workType "article" @default.