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• W1982206892 abstract "Germanium-containing compounds isostructural with naturally occurring silicate garnets have been synthesized dry and at 1 atm of steam by solid state reaction. The general formula for these compounds is A3B2Ge3O12 in which A is divalent Cd, Ca or Mn, and B is trivalent Fe, Al, Cr, Sc or Ga. Of these possible combinations only Mn3Sc2Ge3O12 and Ca3Ga2Ge3O12 could not be prepared in this investigation. X-ray fluorescence analysis indicates that most of the compounds contain less than the stoichiometric amount of Ge. Reaction studies from 800°C to the melting points revealed several phases which could not be identified. Several of the compounds yielded glasses upon quenching of their melts. The determination of cation distribution in Ca3Al2Ge3O12 based on intensity data from X-ray diffraction was inconclusive." @default.
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• W1982206892 date "1961-10-01" @default.
• W1982206892 modified "2023-09-25" @default.
• W1982206892 title "The crystal chemistry of some germanium garnets" @default.
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• W1982206892 doi "https://doi.org/10.1016/0022-3697(61)90208-6" @default.
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