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- W1982245794 abstract "We have developed a new strategy for the preparation of diolides using a cascade of Nicholas reactions. The carboxylic acid nucleophiles in these reactions are virtually unstudied participants in transformations of this type. Using this methodology, a 16-membered cobalt-complexed cyclic diyne is available in 28% yield over eight steps (an average of 85% per step). We can also easily access the uncomplexed diolide in one additional step." @default.
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- W1982245794 date "2005-10-01" @default.
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- W1982245794 title "Nicholas Reactions with Carboxylic Acids for the Synthesis of Macrocyclic Diolides" @default.
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- W1982245794 doi "https://doi.org/10.1021/jo051691q" @default.
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