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- W1982247946 abstract "New spin-crossover iron(III) complexes [FeM(salten)L]X with an alkali ion in a macrocycle have been prepared, and the magnetic properties of the complexes in the solid and in acetonitrile solution have been examined, where M is Li+, Na+, K+, or Rb+, H2salten is 4-aza-heptamethylene-1,7-bis(salicylideneiminate) and L is N-(4-picolyl)-aza-15-crown-5-ether. The spin-crossover behaviors of the iron(III) complexes dependent on temperature in the solid are observed on the Mossbauer spectra and magnetic susceptibilities, and those in acetonitrile on the electronic spectra. The magnetic properties of the complexes in the solid are changed with the species of alkali metal ions included in a macrocycle. Li-complexes show the magnetic moment of 4.00 B.M. at 300 K and 2.19 B.M. at 80 K, and Na-complexes 5.03 B.M. at 300 K and 4.21 B.M. at 80 K. The Mossbauer spectra of Li-complexes show that the interexchange rates of the spin-state transition between high-spin and low-spin states are as fast as the reciprocal of the..." @default.
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- W1982247946 date "1998-12-01" @default.
- W1982247946 modified "2023-09-26" @default.
- W1982247946 title "Effects of the Encapsulation of Alkali Ions into Iron(III) Complexes with a Macrocyclic Ring on Magnetic Properties" @default.
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- W1982247946 doi "https://doi.org/10.1246/bcsj.71.2837" @default.
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