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- W1982254074 abstract "A series of galactose-based surfactants with various structures likely to display new interesting properties were synthesized. Four monocatenary surfactants were elaborated by microwave-assisted galactosylation of undecanol or 10-undecenol. These compounds were slightly soluble in water. Their tensioactive properties were determined at 45 °C. Olefin metathesis was used to synthesize the two single-chain bolaforms from undec-10-enyl galactopyranosides; two pseudomacrocyclic bolaforms were prepared by grafting two carbamates at O-4 and O-4′ sugar positions of the single-chain bolaforms. These four surfactants are insoluble in water and undergo monolayer compression. Cyclization of these bolaforms by olefin metathesis led to macrocyclic surfactant analogues of archaeobacterial membrane components." @default.
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- W1982254074 date "2004-05-01" @default.
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- W1982254074 title "Synthesis and properties of new bolaform and macrocyclic galactose-based surfactants obtained by olefin metathesis" @default.
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- W1982254074 doi "https://doi.org/10.1016/j.carres.2004.03.003" @default.
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