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- W1982266525 endingPage "1226" @default.
- W1982266525 startingPage "1214" @default.
- W1982266525 abstract "The synthesis and reaction chemistry of heterobimetallic FcPPh2AuCl (1) and FcPPh2Au-C≡CR compounds (3a, R = bipy; 3b, R = C6H4-4-C≡N; 3c, R = C5H4N-4; 3d, R = NCN-H; 3e, R = NCN-I; Fc = (η5-C5H5)(η5-C5H4)Fe; bipy = 2,2′-bipyridyl-5-yl; NCN = [C6H2(CH2NMe2)2-2,6]−) toward diverse organometallic molecules is described. In context with this background, 1 was prepared by reacting FcPPh2 with (tht)AuCl (tht = tetrahydrothiophene). The reaction of 1 either with HC≡CR (2a, R = bipy; 2b, R = C6H4-4-C≡N; 2c, R = C5H4N-4) or with the lithium acetylides LiC≡CR (2d, R = NCN-H; 2e, R = NCN-I) gave complexes 3a−3e in good yield. In 1 the gold(I) chloride entity was further reacted with the organometallic alkyne HC≡CMLn (4a, MLn = (η6-C6H5)Cr(CO)3; 4b, MLn = Fc; 4c, MLn = Rc; Rc = (η5-C5H5)(η5-C5H4)Ru) to afford the heterotrimetallic complexes FcPPh2Au-C≡CMLn (5a, MLn = (η6-C6H5)Cr(CO)3; 5b, MLn = Fc; 5c, MLn = Rc) in which three different transition metal atoms are connected via rigid-rod structured carbon-rich units...." @default.
- W1982266525 created "2016-06-24" @default.
- W1982266525 creator A5022173691 @default.
- W1982266525 creator A5029571704 @default.
- W1982266525 creator A5037178014 @default.
- W1982266525 creator A5039877065 @default.
- W1982266525 creator A5028881252 @default.
- W1982266525 date "2008-02-22" @default.
- W1982266525 modified "2023-10-16" @default.
- W1982266525 title "Diphenylphosphinoferrocene Gold(I) Acetylides: Synthesis of Heterotri- and Heterotetrametallic Transition Metal Complexes" @default.
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- W1982266525 doi "https://doi.org/10.1021/om701021y" @default.
- W1982266525 hasPublicationYear "2008" @default.
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