SemOpenAlex |

SemOpenAlex

Matches in SemOpenAlex for { <https://semopenalex.org/work/W1982276449> ?p ?o ?g. }

Showing items 1 to 98 of 98 with 100 items per page.

W1982276449 endingPage "1130" @default.
W1982276449 startingPage "1123" @default.
W1982276449 abstract "The title complex trans-[Cu(sac)2(en)2] (sac = saccharinato, en = ethylenediamine) has been obtained accidentally by the reaction of piperazine (ppz) with [Cu(sac)2(H2O)4]·2H2O in butanol solution. During the reaction, ppz was presumably decomposed to produce en which then coordinated to copper(II) to yield the title complex. trans-[Cu(sac)2(en)2] has been characterized by elemental analysis, IR, UV-VIS, magnetic measurements and single crystal X-ray diffraction. The compound crystallizes in space group (No. 2) and it consists of neutral units linked by bi- and trifurcated N–H···O hydrogen bonds into chains which are further connected by aromatic π–π stacking interactions forming a three-dimensional supramolecular network. The copper(II) ion in [Cu(sac)2(en)2] sits on a inversion centre and is octahedrally coordinated by two neutral en and two anionic sac ligands. An elongated distorted octahedral geometry along the Cu–Nsac bonds is a consequence of the Jahn–Teller effect. The en ligand acts as a bidentate (N,N′) chelating ligand, while sac is N-coordinated. IR and UV spectra and thermal analysis are in agreement with the crystal structure." @default.
W1982276449 created "2016-06-24" @default.
W1982276449 creator A5021150846 @default.
W1982276449 creator A5079001760 @default.
W1982276449 creator A5081805691 @default.
W1982276449 date "2006-07-10" @default.
W1982276449 modified "2023-09-24" @default.
W1982276449 title "Synthesis, crystal structure and properties of trans-[Cu(sac)2(en)2] (sac=saccharinato and en=ethylenediamine)" @default.
W1982276449 cites W1498317611 @default.
W1982276449 cites W1964614233 @default.
W1982276449 cites W1971951524 @default.
W1982276449 cites W1973182498 @default.
W1982276449 cites W1973474598 @default.
W1982276449 cites W1977171567 @default.
W1982276449 cites W1985181156 @default.
W1982276449 cites W1995293060 @default.
W1982276449 cites W2004473258 @default.
W1982276449 cites W2027484758 @default.
W1982276449 cites W2066234906 @default.
W1982276449 cites W2066662943 @default.
W1982276449 cites W2092847925 @default.
W1982276449 cites W2128014410 @default.
W1982276449 cites W2143572725 @default.
W1982276449 cites W2148066840 @default.
W1982276449 cites W2158845389 @default.
W1982276449 cites W2951496146 @default.
W1982276449 doi "https://doi.org/10.1080/00958970500453218" @default.
W1982276449 hasPublicationYear "2006" @default.
W1982276449 type Work @default.
W1982276449 sameAs 1982276449 @default.
W1982276449 citedByCount "7" @default.
W1982276449 countsByYear W19822764492015 @default.
W1982276449 countsByYear W19822764492016 @default.
W1982276449 countsByYear W19822764492017 @default.
W1982276449 countsByYear W19822764492019 @default.
W1982276449 countsByYear W19822764492021 @default.
W1982276449 countsByYear W19822764492022 @default.
W1982276449 crossrefType "journal-article" @default.
W1982276449 hasAuthorship W1982276449A5021150846 @default.
W1982276449 hasAuthorship W1982276449A5079001760 @default.
W1982276449 hasAuthorship W1982276449A5081805691 @default.
W1982276449 hasConcept C112887158 @default.
W1982276449 hasConcept C115624301 @default.
W1982276449 hasConcept C116569031 @default.
W1982276449 hasConcept C170493617 @default.
W1982276449 hasConcept C178516000 @default.
W1982276449 hasConcept C178790620 @default.
W1982276449 hasConcept C179104552 @default.
W1982276449 hasConcept C185592680 @default.
W1982276449 hasConcept C198819137 @default.
W1982276449 hasConcept C2776201271 @default.
W1982276449 hasConcept C2780728571 @default.
W1982276449 hasConcept C32909587 @default.
W1982276449 hasConcept C33347731 @default.
W1982276449 hasConcept C544778455 @default.
W1982276449 hasConcept C55493867 @default.
W1982276449 hasConcept C71240020 @default.
W1982276449 hasConcept C8010536 @default.
W1982276449 hasConcept C93275456 @default.
W1982276449 hasConceptScore W1982276449C112887158 @default.
W1982276449 hasConceptScore W1982276449C115624301 @default.
W1982276449 hasConceptScore W1982276449C116569031 @default.
W1982276449 hasConceptScore W1982276449C170493617 @default.
W1982276449 hasConceptScore W1982276449C178516000 @default.
W1982276449 hasConceptScore W1982276449C178790620 @default.
W1982276449 hasConceptScore W1982276449C179104552 @default.
W1982276449 hasConceptScore W1982276449C185592680 @default.
W1982276449 hasConceptScore W1982276449C198819137 @default.
W1982276449 hasConceptScore W1982276449C2776201271 @default.
W1982276449 hasConceptScore W1982276449C2780728571 @default.
W1982276449 hasConceptScore W1982276449C32909587 @default.
W1982276449 hasConceptScore W1982276449C33347731 @default.
W1982276449 hasConceptScore W1982276449C544778455 @default.
W1982276449 hasConceptScore W1982276449C55493867 @default.
W1982276449 hasConceptScore W1982276449C71240020 @default.
W1982276449 hasConceptScore W1982276449C8010536 @default.
W1982276449 hasConceptScore W1982276449C93275456 @default.
W1982276449 hasIssue "10" @default.
W1982276449 hasLocation W19822764491 @default.
W1982276449 hasOpenAccess W1982276449 @default.
W1982276449 hasPrimaryLocation W19822764491 @default.
W1982276449 hasRelatedWork W1970358650 @default.
W1982276449 hasRelatedWork W1980640176 @default.
W1982276449 hasRelatedWork W1987208176 @default.
W1982276449 hasRelatedWork W2089341551 @default.
W1982276449 hasRelatedWork W2262641225 @default.
W1982276449 hasRelatedWork W2327737461 @default.
W1982276449 hasRelatedWork W2392522322 @default.
W1982276449 hasRelatedWork W3148323916 @default.
W1982276449 hasRelatedWork W4239653929 @default.
W1982276449 hasRelatedWork W4242565736 @default.
W1982276449 hasVolume "59" @default.
W1982276449 isParatext "false" @default.
W1982276449 isRetracted "false" @default.
W1982276449 magId "1982276449" @default.
W1982276449 workType "article" @default.