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• W1982280780 abstract "Bromobenzene oxidatively adds to the palladium(0) compound Pd(PCy3)2 to give cleanly the palladium(II) product trans-PdBr(Ph)(PCy3)2. Kinetics studies of this reaction under pseudo-first-order conditions (excess PhBr) as well as in the presence of 1 molar equiv of PCy3 or of added bromide ion (as the toluene-soluble tetraoctylphosphonium salt) have been carried out. We find that oxidative addition is first-order in palladium and that, in the absence of added PCy3, the reaction involves both the 2:1 species Pd(PCy3)2 and the 1:1 species Pd(PCy3). Interestingly, added PCy3 results in inhibition of oxidative addition both by decreasing the relative amount of the reactive 1:1 compound and by converting much of the palladium(0) to the kinetically less active 3:1 compound Pd(PCy3)3. Added bromide ion has essentially no effect on the rate, surprising in view of previous literature reports." @default.
• W1982280780 created "2016-06-24" @default.
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• W1982280780 creator A5030031569 @default.
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• W1982280780 date "2009-11-10" @default.
• W1982280780 modified "2023-09-27" @default.
• W1982280780 title "A Kinetics Study of the Oxidative Addition of Bromobenzene to Pd(PCy₃)₂ (Cy = cyclohexyl) in a Nonpolar Medium: The Influence on Rates of Added PCy₃ and Bromide Ion" @default.
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• W1982280780 doi "https://doi.org/10.1021/om900679w" @default.
• W1982280780 hasPublicationYear "2009" @default.
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