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• W1982361346 startingPage "957" @default.
• W1982361346 abstract "Extraction kinetic mechanism of Ni(II) with 2-(5-bromo-2-pyridylazo)-5-diethylaminophenol (5-Br-PADAP) was studied by a high-speed stirring spectrophotometry in heptane/water and toluene/water systems. The experimental results revealed that a rate-determining step was the 1 : 1 chelate formation of Ni2+ with 5-Br-PADAP adsorbed at the interface. In situ spectrophotometry of the heptane/water interface proved the formation of Ni(II) complex at the interface. The preferential adsorption of 5-Br-PADAP and its Ni(II) complex in heptane/water interface was correlated with the lower distribution constant in heptane/water than that in toluene/water. Molecular dynamics simulation could reproduce the preferential adsorptivity in heptane/water interface and then the higher reactivity with Ni2+ in the interface. The observed formation rate constants of the Ni(II) complex in bulk aqueous phase and the interfaces were smaller than those expected from the Eigen mechanism. Molecular mechanics calculation supported the ring-closure mechanism, previously postulated as the rate-determining step." @default.
• W1982361346 created "2016-06-24" @default.
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• W1982361346 date "1997-05-01" @default.
• W1982361346 modified "2023-09-27" @default.
• W1982361346 title "Interfacial Mechanism in the Extraction Kinetics of Ni(II) with 2-(5-Bromo-2-pyridylazo)-5-diethylaminophenol and Molecular Dynamics Simulation of Interfacial Reactivity of the Ligand" @default.
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• W1982361346 doi "https://doi.org/10.1246/bcsj.70.957" @default.
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