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• W1982376783 abstract "Langmuir-Blodgett films have been made with 3-n-hexadecylpyrrole and 3-n-octadecylpyrrole monomers and copolymers with unsubstituted pyrrole made by chemical polymerization at the air-water interface on a subphase containing FeCl3. Langmuir-Blodgett films consisting of mixtures of stearic acid and alkylsubstituted polythiophenes have also been made as bilayer films. The orientation of single and multilayer films on platinum substrates have been studied by Near Edge X-ray Absorption Fine Structure Spectroscopy which also gives information about charge transfer interactions between the aromatic groups and the metallic substrates. The alkylsubstituted pyrroles form highly ordered two-dimensional structures. FeCl3 initiated copolymerization with unsubstituted pyrrole leads to a more disordered system. In the case of polythiophene-stearic acid bilayers, the stearic acid layers are highly ordered. The poly(alkyl thiophene) layers sandwiched between stearic acid layers, on the other hand, exhibit random orientation of the thiophene moieties." @default.
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• W1982376783 date "1989-01-01" @default.
• W1982376783 modified "2023-10-16" @default.
• W1982376783 title "Highly ordered thin films of polyheterocycles: A synchrotron radiation study of polypyrrole and polythiophene Langmuir-Blodgett films" @default.
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• W1982376783 doi "https://doi.org/10.1016/0379-6779(89)90526-2" @default.
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