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- W1982391719 abstract "Abstract Three Mn(III,III) complexes containing dibenzoylmethane (dbm), Mn 2 (OMe) 2 (dbm) 2 (ClH 2 CCOO) 2 ( 1 ), Mn 2 (OMe) 2 (dbm) 2 (Cl 2 HCCOO) 2 ( 2 ) and Mn 2 (OMe) 2 (dbm) 2 (Cl 3 CCOO) 2 ( 3 ) were synthesized. Crystal structure determination and magnetic characterization were done for 2 . The Mn⋯Mn distance in complex 2 is 2.865 A. It exhibits antiferromagnetic coupling with exchange parameter | J | = 20.4 cm −1 ( H = −2 JS A S B ). All three complexes, though insoluble in common solvents, catalyse the disproportionation of hydrogen peroxide when dispersed on silica gel with turnover numbers ∼150–300. DFT simulations showed that bridging moieties have remarkable effect on intermetallic distances in dimanganese(III,III) complexes." @default.
- W1982391719 created "2016-06-24" @default.
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- W1982391719 date "2011-06-01" @default.
- W1982391719 modified "2023-09-26" @default.
- W1982391719 title "Structure, magnetic properties, catalase activity and DFT studies of [Mn2(μ-RCOO)2(μ-OR)2]2+ type dinuclear manganese(III,III) complexes" @default.
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- W1982391719 doi "https://doi.org/10.1016/j.ica.2011.03.004" @default.
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