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- W1982400481 abstract "The tethered aminohydroxylation of cyclic allylic carbamates is described using catalytic amounts of potassium osmate. The mechanism of reaction involves formation of an imido-osmium complex which adds intramolecularly to alkenes with complete control of both regio- and stereoselectivity: the formation of syn-aminodiol motifs is now straightforward using this chemistry. Proof of the mechanism was obtained with an X-ray crystal structure of an azaglycolate osmate ester intermediate." @default.
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- W1982400481 date "2002-10-10" @default.
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- W1982400481 title "The Tethered Aminohydroxylation (TA) of Cyclic Allylic Carbamates" @default.
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- W1982400481 doi "https://doi.org/10.1021/ja0276117" @default.
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