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- W1982403253 abstract "The asymmetric unit of the title coordination polymer, [Cu(C18H16Br2N2O2)]n, consists of a Schiff base complex in which a crystallographic twofold rotation axis bisects the central C—C bonds of the n-butyl spacers of the designated Schiff base ligands, making symmetry-related dimer units, which are twisted around CuII atoms in a bis-bidentate coordination mode. In the crystal, these dimeric units are connected through Cu—O bonds, forming one-dimensional coordination polymers, which propagate along [001]. The CuII atom adopts a square-based pyramidal coordination geometry, being coordinated by two N and two O atoms of symmetry-related ligands and by a third O atom of a neighboring complex. Furthermore, intermolecular π–π interactions [centroid–centroid distance = 3.786 (2) Å] and C—H⋯O interactions stabilize the crystal packing." @default.
- W1982403253 created "2016-06-24" @default.
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- W1982403253 date "2011-03-26" @default.
- W1982403253 modified "2023-09-28" @default.
- W1982403253 title "<i>catena</i>-Poly[copper(II)-{μ<sub>3</sub>-4,4′-dibromo-2,2′-[butane-1,4-diylbis(nitrilomethanylylidene)]diphenolato-κ<sup>4</sup><i>N</i>,<i>O</i>:<i>N</i>′,<i>O</i>′:<i>O</i>′}]" @default.
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- W1982403253 doi "https://doi.org/10.1107/s1600536811009949" @default.
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