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- W1982428305 abstract "The title compound is obtained in 80% yield by silylation of the lithium salt of diethyl 1-methylthiomethylphosphonate. Other approaches involving sulfenylation of diethyl 1-trimethylsilylmethylphosphonate or the Arbuzov reaction of triethyl phosphite with bromo(methylthio)(trimethylsilyl)methane are less efficient. Aldehydes react with the lithium salt of diethyl (methylthio)(trimethylsilyl)methylphosphonate to give the corresponding 1-methylthioethenylphosphonates in good yields (60-85%) while the reaction with ketones is more complex and Peterson reaction products are formed in very low yields. Methylation, silylation, sulfenylation, and oxidation of the title compound are also described." @default.
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- W1982428305 date "1989-01-01" @default.
- W1982428305 modified "2023-10-12" @default.
- W1982428305 title "Synthesis and Reactivity of Diethyl (Methylthio)(trimethylsilyl)methylphosphonate" @default.
- W1982428305 doi "https://doi.org/10.1055/s-1989-27163" @default.
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