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- W1982474811 abstract "By chlorination of polyvinyltrimethylsilane (PVTMS) by the action of molecular chlorine in a CCl4 solution, initiated by visible light chlorinated PVTMS samples were obtained containing chlorine of n = 4·5, 18 and 78 Cl atoms per 100 Si atoms. Permeability factor P, coefficients of diffusion D and solubility σ of a number of gases (O2, N2, CH4, C2H2, C2H4, SO2, CH3Cl, C2H3Cl) were determined with different degrees of chlorination. The rate of reduction of D with an increase in the degree of chlorination is dependent of the type of penetrating substance. For constant gases P decreases 4-fold with n = 78, whereas for SO2, CH3Cl and C2H3Cl P shows a much slighter dependence on n, which is due to the effect of the degree of chlorination of PVTMS on the coefficient of solubility of polar compounds." @default.
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- W1982474811 date "1980-01-01" @default.
- W1982474811 modified "2023-09-26" @default.
- W1982474811 title "Gas permeability of chlorinated polyvinyl trimethylsilane" @default.
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- W1982474811 doi "https://doi.org/10.1016/0032-3950(80)90032-5" @default.
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