Matches in SemOpenAlex for { <https://semopenalex.org/work/W1982482583> ?p ?o ?g. }
Showing items 1 to 100 of
100
with 100 items per page.
- W1982482583 endingPage "2466" @default.
- W1982482583 startingPage "2457" @default.
- W1982482583 abstract "Secondary Hydroxyalkylphosphanes: Synthesis and Characterization of Mono-, Bis- and Trisalkoxyphosphane-substituted Zirconium Complexes and the Heterobimetallic Trinuclear Complex [Cp2Zr{O(CH2)3PHMes(AuCl)}2] The secondary hydroxyalkylphosphanes RPHCH2OH [R = 2,4,6-Me3C6H2 (Mes) (1), 2,4,6-iPr3C6H2 (Tipp) (2)], 1-AdPH-2-OH-cyclo-C6H10 (3) and RPH(CH2)3OH [R = Ph (4), Mes (5), Tipp (6), Cy (7), tBu (8)] were obtained from primary phosphanes RPH2 and formaldehyde (1, 2) or from LiPHR and cyclohexene oxide (3) or trimethylene oxide (4-8). Starting from 5 or 7 and [CpR2ZrMe2] [CpR = C5EtMe4 (Cp°), C5H5 (Cp), C5MeH4 (Cp′)], the monoalkoxyphosphane-substituted zirconocene complexes [CpR2Zr(Me){O(CH2)3PHMes}] [CpR = Cp° (9), Cp (10)] were prepared. With [CpR2ZrCl2], the bisalkoxyphosphane-substituted complexes [Cp′2Zr{O(CH2)3PHMes}2] (11) and [Cp2Zr{O(CH2)3PHCy}2] (12) are obtained, and with [TpRZrCl3], the trisalkoxyphosphane-substituted zirconium complexes [TpRZr{O(CH2)3PHMes}3] [TpR = trispyrazolylborato (Tp) (13), TpR = tris(3,5-dimethyl)pyrazolylborato (Tp*) (14)] are prepared. The reaction of 5 with [AuCl(tht)] (tht = tetrahydrothiophene) yielded the mononuclear complex [AuCl{PHMes(CH2)3OH}] (15). The trinuclear complex [Cp2Zr{O(CH2)3PHMes(AuCl)}2] (16) was obtained from [Cp2ZrCl2] and 15. Compounds 1-16 were characterized spectroscopically (1H-, 31P-, 13C-NMR; IR; MS) and compound 2 also by crystal structure determination. The bis- and trisalkoxyphosphane-substituted complexes 11-14 and 16 were obtained as mixtures of two diastereomers which could not be separated." @default.
- W1982482583 created "2016-06-24" @default.
- W1982482583 creator A5011359523 @default.
- W1982482583 creator A5037784379 @default.
- W1982482583 creator A5075409783 @default.
- W1982482583 date "2005-09-01" @default.
- W1982482583 modified "2023-09-26" @default.
- W1982482583 title "Sekundäre Hydroxyalkylphosphane: Synthese und Charakterisierung mono-, bis- und trisalkoxyphosphan-substituierter Zirconiumkomplexe und des heterobimetallischen Dreikernkomplexes [Cp2Zr{O(CH2)3PHMes(AuCl)}2]" @default.
- W1982482583 cites W1965476205 @default.
- W1982482583 cites W1966821473 @default.
- W1982482583 cites W1968533865 @default.
- W1982482583 cites W1970626388 @default.
- W1982482583 cites W1980624015 @default.
- W1982482583 cites W1984596374 @default.
- W1982482583 cites W1987432691 @default.
- W1982482583 cites W1993193868 @default.
- W1982482583 cites W1995943318 @default.
- W1982482583 cites W2000137578 @default.
- W1982482583 cites W2003907113 @default.
- W1982482583 cites W2014062498 @default.
- W1982482583 cites W2035419879 @default.
- W1982482583 cites W2059020082 @default.
- W1982482583 cites W2059652808 @default.
- W1982482583 cites W2061816981 @default.
- W1982482583 cites W2062356105 @default.
- W1982482583 cites W2064056562 @default.
- W1982482583 cites W2067500340 @default.
- W1982482583 cites W2071262481 @default.
- W1982482583 cites W2073506728 @default.
- W1982482583 cites W2083444125 @default.
- W1982482583 cites W2085662793 @default.
- W1982482583 cites W2086924857 @default.
- W1982482583 cites W2097729812 @default.
- W1982482583 cites W2132003992 @default.
- W1982482583 cites W2145476875 @default.
- W1982482583 cites W2332426116 @default.
- W1982482583 cites W2949533222 @default.
- W1982482583 cites W2950756007 @default.
- W1982482583 cites W2950847930 @default.
- W1982482583 cites W2951643603 @default.
- W1982482583 cites W2953172985 @default.
- W1982482583 cites W3004851396 @default.
- W1982482583 cites W3138730820 @default.
- W1982482583 cites W3195202782 @default.
- W1982482583 cites W4244726385 @default.
- W1982482583 cites W4250478122 @default.
- W1982482583 doi "https://doi.org/10.1002/zaac.200500276" @default.
- W1982482583 hasPublicationYear "2005" @default.
- W1982482583 type Work @default.
- W1982482583 sameAs 1982482583 @default.
- W1982482583 citedByCount "0" @default.
- W1982482583 crossrefType "journal-article" @default.
- W1982482583 hasAuthorship W1982482583A5011359523 @default.
- W1982482583 hasAuthorship W1982482583A5037784379 @default.
- W1982482583 hasAuthorship W1982482583A5075409783 @default.
- W1982482583 hasConcept C115624301 @default.
- W1982482583 hasConcept C138716334 @default.
- W1982482583 hasConcept C155647269 @default.
- W1982482583 hasConcept C161790260 @default.
- W1982482583 hasConcept C178790620 @default.
- W1982482583 hasConcept C185592680 @default.
- W1982482583 hasConcept C2779484182 @default.
- W1982482583 hasConcept C2779879930 @default.
- W1982482583 hasConcept C2780477052 @default.
- W1982482583 hasConcept C534791751 @default.
- W1982482583 hasConcept C71240020 @default.
- W1982482583 hasConcept C8010536 @default.
- W1982482583 hasConceptScore W1982482583C115624301 @default.
- W1982482583 hasConceptScore W1982482583C138716334 @default.
- W1982482583 hasConceptScore W1982482583C155647269 @default.
- W1982482583 hasConceptScore W1982482583C161790260 @default.
- W1982482583 hasConceptScore W1982482583C178790620 @default.
- W1982482583 hasConceptScore W1982482583C185592680 @default.
- W1982482583 hasConceptScore W1982482583C2779484182 @default.
- W1982482583 hasConceptScore W1982482583C2779879930 @default.
- W1982482583 hasConceptScore W1982482583C2780477052 @default.
- W1982482583 hasConceptScore W1982482583C534791751 @default.
- W1982482583 hasConceptScore W1982482583C71240020 @default.
- W1982482583 hasConceptScore W1982482583C8010536 @default.
- W1982482583 hasIssue "12" @default.
- W1982482583 hasLocation W19824825831 @default.
- W1982482583 hasOpenAccess W1982482583 @default.
- W1982482583 hasPrimaryLocation W19824825831 @default.
- W1982482583 hasRelatedWork W1600902618 @default.
- W1982482583 hasRelatedWork W1970917829 @default.
- W1982482583 hasRelatedWork W1982482583 @default.
- W1982482583 hasRelatedWork W2007006670 @default.
- W1982482583 hasRelatedWork W2045597803 @default.
- W1982482583 hasRelatedWork W2599646435 @default.
- W1982482583 hasRelatedWork W2767498246 @default.
- W1982482583 hasRelatedWork W2901710390 @default.
- W1982482583 hasRelatedWork W2949518215 @default.
- W1982482583 hasRelatedWork W2952351308 @default.
- W1982482583 hasVolume "631" @default.
- W1982482583 isParatext "false" @default.
- W1982482583 isRetracted "false" @default.
- W1982482583 magId "1982482583" @default.
- W1982482583 workType "article" @default.