Matches in SemOpenAlex for { <https://semopenalex.org/work/W1982483037> ?p ?o ?g. }
- W1982483037 endingPage "976" @default.
- W1982483037 startingPage "967" @default.
- W1982483037 abstract "The curing of drying oils at 60°C has been investigated by Fourier transform infrared spectroscopy and Fourier transform Raman analysis of linseed oil and poppyseed oil. In the first step, hydroperoxides are formed (broad vibration band centered around 3425 cm−1) with concomitant conjugation and cis-trans isomerization of the double bonds (disappearance of cis bands at 3011 and 716 cm−1, appearance of trans conjugated and trans nonconjugated bands at 987 and 970 cm−1). The subsequent decomposition of hydroperoxides in the presence of oxygen leads to the formation of alcohols (nitrite band at 779 cm−1 after nitrogen monoxide treatment), aldehydes (bands at 2810 and 2717 cm−1 in gas phase), ketones (saturated and unsaturated at 1720 and 1698 cm−1, respectively), carboxylic acids (saturated and unsaturated acid fluorides identified at 1843 and 1810 cm−1 after SF4 treatment), and peresters or γ-lactones (near 1770 cm−1). A rapid decrease in the double-bond concentration is recorded when curing continues, and the formation of epoxides, characterized by a vibration band at 885 cm−1, is observed. Thermolysis experiments have suggested the proposal of a reaction of addition of peroxyl radicals on the conjugated double bonds as a probable mechanism. This mechanism explains both the rapid disappearance of conjugated double bonds and the formation of epoxides as intermediate products observed in the initial step of curing." @default.
- W1982483037 created "2016-06-24" @default.
- W1982483037 creator A5008674676 @default.
- W1982483037 creator A5034893570 @default.
- W1982483037 creator A5065804423 @default.
- W1982483037 date "1999-08-01" @default.
- W1982483037 modified "2023-10-18" @default.
- W1982483037 title "Long-term behavior of oil-based varnishes and paints I. Spectroscopic analysis of curing drying oils" @default.
- W1982483037 cites W1966481028 @default.
- W1982483037 cites W1971297861 @default.
- W1982483037 cites W1974586838 @default.
- W1982483037 cites W1983719630 @default.
- W1982483037 cites W1999104028 @default.
- W1982483037 cites W2000183077 @default.
- W1982483037 cites W2000542701 @default.
- W1982483037 cites W2002412531 @default.
- W1982483037 cites W2003527499 @default.
- W1982483037 cites W2011416497 @default.
- W1982483037 cites W2012831050 @default.
- W1982483037 cites W2013313557 @default.
- W1982483037 cites W2019557753 @default.
- W1982483037 cites W2019787330 @default.
- W1982483037 cites W2030173411 @default.
- W1982483037 cites W2035914797 @default.
- W1982483037 cites W2036312778 @default.
- W1982483037 cites W2039929577 @default.
- W1982483037 cites W204293396 @default.
- W1982483037 cites W2051022869 @default.
- W1982483037 cites W2051350716 @default.
- W1982483037 cites W2053503539 @default.
- W1982483037 cites W2055402177 @default.
- W1982483037 cites W2057794310 @default.
- W1982483037 cites W2065526754 @default.
- W1982483037 cites W2073110598 @default.
- W1982483037 cites W2075640973 @default.
- W1982483037 cites W2078065279 @default.
- W1982483037 cites W2082989058 @default.
- W1982483037 cites W2085222326 @default.
- W1982483037 cites W2089415788 @default.
- W1982483037 cites W2090857972 @default.
- W1982483037 cites W2091567144 @default.
- W1982483037 cites W2131294647 @default.
- W1982483037 cites W2153149852 @default.
- W1982483037 cites W2162920620 @default.
- W1982483037 cites W2312770747 @default.
- W1982483037 cites W2313449776 @default.
- W1982483037 cites W2315541156 @default.
- W1982483037 cites W2329551262 @default.
- W1982483037 cites W2342925464 @default.
- W1982483037 cites W3135204810 @default.
- W1982483037 cites W4211242258 @default.
- W1982483037 cites W4235632627 @default.
- W1982483037 doi "https://doi.org/10.1007/s11746-999-0114-3" @default.
- W1982483037 hasPublicationYear "1999" @default.
- W1982483037 type Work @default.
- W1982483037 sameAs 1982483037 @default.
- W1982483037 citedByCount "100" @default.
- W1982483037 countsByYear W19824830372012 @default.
- W1982483037 countsByYear W19824830372013 @default.
- W1982483037 countsByYear W19824830372014 @default.
- W1982483037 countsByYear W19824830372015 @default.
- W1982483037 countsByYear W19824830372016 @default.
- W1982483037 countsByYear W19824830372017 @default.
- W1982483037 countsByYear W19824830372018 @default.
- W1982483037 countsByYear W19824830372019 @default.
- W1982483037 countsByYear W19824830372020 @default.
- W1982483037 countsByYear W19824830372021 @default.
- W1982483037 countsByYear W19824830372022 @default.
- W1982483037 countsByYear W19824830372023 @default.
- W1982483037 crossrefType "journal-article" @default.
- W1982483037 hasAuthorship W1982483037A5008674676 @default.
- W1982483037 hasAuthorship W1982483037A5034893570 @default.
- W1982483037 hasAuthorship W1982483037A5065804423 @default.
- W1982483037 hasConcept C112613896 @default.
- W1982483037 hasConcept C120665830 @default.
- W1982483037 hasConcept C121332964 @default.
- W1982483037 hasConcept C126661725 @default.
- W1982483037 hasConcept C127413603 @default.
- W1982483037 hasConcept C132976073 @default.
- W1982483037 hasConcept C153642686 @default.
- W1982483037 hasConcept C160892712 @default.
- W1982483037 hasConcept C161790260 @default.
- W1982483037 hasConcept C178790620 @default.
- W1982483037 hasConcept C185592680 @default.
- W1982483037 hasConcept C188027245 @default.
- W1982483037 hasConcept C40003534 @default.
- W1982483037 hasConcept C42360764 @default.
- W1982483037 hasConcept C521977710 @default.
- W1982483037 hasConcept C68381374 @default.
- W1982483037 hasConcept C75473681 @default.
- W1982483037 hasConceptScore W1982483037C112613896 @default.
- W1982483037 hasConceptScore W1982483037C120665830 @default.
- W1982483037 hasConceptScore W1982483037C121332964 @default.
- W1982483037 hasConceptScore W1982483037C126661725 @default.
- W1982483037 hasConceptScore W1982483037C127413603 @default.
- W1982483037 hasConceptScore W1982483037C132976073 @default.
- W1982483037 hasConceptScore W1982483037C153642686 @default.
- W1982483037 hasConceptScore W1982483037C160892712 @default.