FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W1982483541> ?p ?o ?g. }

• W1982483541 endingPage "16525" @default.
• W1982483541 startingPage "16514" @default.
• W1982483541 abstract "For practical applications of solid/solution adsorption processes, the kinetics of these processes is at least as much essential as their features at equilibrium. Meanwhile, the general understanding of this kinetics and its corresponding theoretical description are far behind the understanding and the level of theoretical interpretation of adsorption equilibria in these systems. The Lagergren empirical equation proposed at the end of 19th century to describe the kinetics of solute sorption at the solid/solution interfaces has been the most widely used kinetic equation until now. This equation has also been called the pseudo-first order kinetic equation because it was intuitively associated with the model of one-site occupancy adsorption kinetics governed by the rate of surface reaction. More recently, its generalization for the two-sites-occupancy adsorption was proposed and called the pseudo-second-order kinetic equation. However, the general use and the wide applicability of these empirical equations during more than one century have not resulted in a corresponding fundamental search for their theoretical origin. Here the first theoretical development of these equations is proposed, based on applying the new fundamental approach to kinetics of interfacial transport called the Statistical Rate Theory. It is shown that these empirical equations are simplified forms of a more general equation developed here, for the case when the adsorption kinetics is governed by the rate of surface reactions. The features of that general equation are shown by presenting exhaustive model investigations, and the applicability of that equation is tested by presenting a quantitative analysis of some experimental data reported in the literature." @default.
• W1982483541 created "2016-06-24" @default.
• W1982483541 creator A5014842582 @default.
• W1982483541 creator A5091413677 @default.
• W1982483541 date "2006-08-01" @default.
• W1982483541 modified "2023-10-12" @default.
• W1982483541 title "Kinetics of Solute Adsorption at Solid/Solution Interfaces: A Theoretical Development of the Empirical Pseudo-First and Pseudo-Second Order Kinetic Rate Equations, Based on Applying the Statistical Rate Theory of Interfacial Transport" @default.
• W1982483541 cites W1965492349 @default.
• W1982483541 cites W1976414070 @default.
• W1982483541 cites W1980975837 @default.
• W1982483541 cites W1991994757 @default.
• W1982483541 cites W1995670775 @default.
• W1982483541 cites W2001898003 @default.
• W1982483541 cites W2003435029 @default.
• W1982483541 cites W2003679201 @default.
• W1982483541 cites W2012536709 @default.
• W1982483541 cites W2015837394 @default.
• W1982483541 cites W2024206531 @default.
• W1982483541 cites W2025200130 @default.
• W1982483541 cites W2028505983 @default.
• W1982483541 cites W2037562176 @default.
• W1982483541 cites W2042947564 @default.
• W1982483541 cites W2043779111 @default.
• W1982483541 cites W2047521330 @default.
• W1982483541 cites W2067951369 @default.
• W1982483541 cites W2082359244 @default.
• W1982483541 cites W2083287842 @default.
• W1982483541 cites W2087753317 @default.
• W1982483541 cites W2088425655 @default.
• W1982483541 cites W2095482543 @default.
• W1982483541 cites W2096479883 @default.
• W1982483541 cites W2112017750 @default.
• W1982483541 cites W2137750292 @default.
• W1982483541 cites W2146120114 @default.
• W1982483541 cites W394896863 @default.
• W1982483541 doi "https://doi.org/10.1021/jp061779n" @default.
• W1982483541 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/17201454" @default.
• W1982483541 hasPublicationYear "2006" @default.
• W1982483541 type Work @default.
• W1982483541 sameAs 1982483541 @default.
• W1982483541 citedByCount "277" @default.
• W1982483541 countsByYear W19824835412012 @default.
• W1982483541 countsByYear W19824835412013 @default.
• W1982483541 countsByYear W19824835412014 @default.
• W1982483541 countsByYear W19824835412015 @default.
• W1982483541 countsByYear W19824835412016 @default.
• W1982483541 countsByYear W19824835412017 @default.
• W1982483541 countsByYear W19824835412018 @default.
• W1982483541 countsByYear W19824835412019 @default.
• W1982483541 countsByYear W19824835412020 @default.
• W1982483541 countsByYear W19824835412021 @default.
• W1982483541 countsByYear W19824835412022 @default.
• W1982483541 countsByYear W19824835412023 @default.
• W1982483541 crossrefType "journal-article" @default.
• W1982483541 hasAuthorship W1982483541A5014842582 @default.
• W1982483541 hasAuthorship W1982483541A5091413677 @default.
• W1982483541 hasConcept C111163200 @default.
• W1982483541 hasConcept C121332964 @default.
• W1982483541 hasConcept C121864883 @default.
• W1982483541 hasConcept C147789679 @default.
• W1982483541 hasConcept C148898269 @default.
• W1982483541 hasConcept C150394285 @default.
• W1982483541 hasConcept C185592680 @default.
• W1982483541 hasConcept C58445606 @default.
• W1982483541 hasConcept C74650414 @default.
• W1982483541 hasConcept C97355855 @default.
• W1982483541 hasConceptScore W1982483541C111163200 @default.
• W1982483541 hasConceptScore W1982483541C121332964 @default.
• W1982483541 hasConceptScore W1982483541C121864883 @default.
• W1982483541 hasConceptScore W1982483541C147789679 @default.
• W1982483541 hasConceptScore W1982483541C148898269 @default.
• W1982483541 hasConceptScore W1982483541C150394285 @default.
• W1982483541 hasConceptScore W1982483541C185592680 @default.
• W1982483541 hasConceptScore W1982483541C58445606 @default.
• W1982483541 hasConceptScore W1982483541C74650414 @default.
• W1982483541 hasConceptScore W1982483541C97355855 @default.
• W1982483541 hasIssue "33" @default.
• W1982483541 hasLocation W19824835411 @default.
• W1982483541 hasLocation W19824835412 @default.
• W1982483541 hasOpenAccess W1982483541 @default.
• W1982483541 hasPrimaryLocation W19824835411 @default.
• W1982483541 hasRelatedWork W1990321110 @default.
• W1982483541 hasRelatedWork W2020181012 @default.
• W1982483541 hasRelatedWork W2030790314 @default.
• W1982483541 hasRelatedWork W2089914422 @default.
• W1982483541 hasRelatedWork W2093229947 @default.
• W1982483541 hasRelatedWork W2348837818 @default.
• W1982483541 hasRelatedWork W2377041589 @default.
• W1982483541 hasRelatedWork W2384943004 @default.
• W1982483541 hasRelatedWork W2771644376 @default.
• W1982483541 hasRelatedWork W4220670021 @default.
• W1982483541 hasVolume "110" @default.
• W1982483541 isParatext "false" @default.
• W1982483541 isRetracted "false" @default.
• W1982483541 magId "1982483541" @default.
• W1982483541 workType "article" @default.