Matches in SemOpenAlex for { <https://semopenalex.org/work/W1982484776> ?p ?o ?g. }
Showing items 1 to 74 of
74
with 100 items per page.
- W1982484776 abstract "The hypervalent iodine oxidative decarboxylation of homocubyl and cubyl mono- and di-carboxylic acids is reported; the carboxylic acid is treated with PhI(OAc)2CC14-I2 under irradiation conditions and 80-90% of the derived iodo compound is obtained. Systematic functionalization of cubane is an important synthetic goal. The two main methods of cubane synthesis involve sequential Favorskii ring contractions to yield first a homocubyl carboxylic acid, and theh after a second Favorskii reaction, a 1,41,2 or 1,33 cubyl dicarboxylic acid. As a consequence of this synthetic procedure the carboxy group is a logical starting functionality for subsequent synthetic transformation in the cubyl ring system. The carboxy group has been converted ,into a nitro group in the synthesis of 1,4-dinitrocubane4 and halogenodecarboxylation has been effected.596 In a basically different approach Eaton et al., used ortho-lithiation of the der td carboxamide etc a site for ortho-iodination.7 Introduction of an iodo group onto the cubyl system is especially desirable because hypervalent iodine synthetic methodology may be employed in order to effect displacement reactions. This scheme has been successfully applied by Eaton et al.8 in tim cubyl system for R-IC12+ R-C1 R-I(OAC)2+ R-OAc where R=1- iodo-2-N,N-di-isopropylcarbox-amido-5-methylcubane." @default.
- W1982484776 created "2016-06-24" @default.
- W1982484776 creator A5018749122 @default.
- W1982484776 creator A5075816930 @default.
- W1982484776 creator A5077908674 @default.
- W1982484776 date "1988-05-09" @default.
- W1982484776 modified "2023-09-23" @default.
- W1982484776 title "Hypervalent Iodine Iodinative Decarboxylation Of Cubyl And Homocubyl Carboxylic Acids" @default.
- W1982484776 doi "https://doi.org/10.1117/12.943749" @default.
- W1982484776 hasPublicationYear "1988" @default.
- W1982484776 type Work @default.
- W1982484776 sameAs 1982484776 @default.
- W1982484776 citedByCount "0" @default.
- W1982484776 crossrefType "proceedings-article" @default.
- W1982484776 hasAuthorship W1982484776A5018749122 @default.
- W1982484776 hasAuthorship W1982484776A5075816930 @default.
- W1982484776 hasAuthorship W1982484776A5077908674 @default.
- W1982484776 hasConcept C115624301 @default.
- W1982484776 hasConcept C155647269 @default.
- W1982484776 hasConcept C161790260 @default.
- W1982484776 hasConcept C178790620 @default.
- W1982484776 hasConcept C181199279 @default.
- W1982484776 hasConcept C185592680 @default.
- W1982484776 hasConcept C2779074116 @default.
- W1982484776 hasConcept C2779634684 @default.
- W1982484776 hasConcept C2780378348 @default.
- W1982484776 hasConcept C2780595602 @default.
- W1982484776 hasConcept C2780750454 @default.
- W1982484776 hasConcept C539932907 @default.
- W1982484776 hasConcept C65973085 @default.
- W1982484776 hasConcept C71240020 @default.
- W1982484776 hasConcept C96149497 @default.
- W1982484776 hasConceptScore W1982484776C115624301 @default.
- W1982484776 hasConceptScore W1982484776C155647269 @default.
- W1982484776 hasConceptScore W1982484776C161790260 @default.
- W1982484776 hasConceptScore W1982484776C178790620 @default.
- W1982484776 hasConceptScore W1982484776C181199279 @default.
- W1982484776 hasConceptScore W1982484776C185592680 @default.
- W1982484776 hasConceptScore W1982484776C2779074116 @default.
- W1982484776 hasConceptScore W1982484776C2779634684 @default.
- W1982484776 hasConceptScore W1982484776C2780378348 @default.
- W1982484776 hasConceptScore W1982484776C2780595602 @default.
- W1982484776 hasConceptScore W1982484776C2780750454 @default.
- W1982484776 hasConceptScore W1982484776C539932907 @default.
- W1982484776 hasConceptScore W1982484776C65973085 @default.
- W1982484776 hasConceptScore W1982484776C71240020 @default.
- W1982484776 hasConceptScore W1982484776C96149497 @default.
- W1982484776 hasLocation W19824847761 @default.
- W1982484776 hasOpenAccess W1982484776 @default.
- W1982484776 hasPrimaryLocation W19824847761 @default.
- W1982484776 hasRelatedWork W2000784498 @default.
- W1982484776 hasRelatedWork W2015586920 @default.
- W1982484776 hasRelatedWork W2019323087 @default.
- W1982484776 hasRelatedWork W2022713576 @default.
- W1982484776 hasRelatedWork W2065904061 @default.
- W1982484776 hasRelatedWork W2124280893 @default.
- W1982484776 hasRelatedWork W2125876664 @default.
- W1982484776 hasRelatedWork W2141355440 @default.
- W1982484776 hasRelatedWork W2227908646 @default.
- W1982484776 hasRelatedWork W243558439 @default.
- W1982484776 hasRelatedWork W2724602499 @default.
- W1982484776 hasRelatedWork W2950044413 @default.
- W1982484776 hasRelatedWork W2950643617 @default.
- W1982484776 hasRelatedWork W2951162188 @default.
- W1982484776 hasRelatedWork W2951419526 @default.
- W1982484776 hasRelatedWork W2951648456 @default.
- W1982484776 hasRelatedWork W2951762566 @default.
- W1982484776 hasRelatedWork W2951811624 @default.
- W1982484776 hasRelatedWork W2951943314 @default.
- W1982484776 hasRelatedWork W2952779590 @default.
- W1982484776 isParatext "false" @default.
- W1982484776 isRetracted "false" @default.
- W1982484776 magId "1982484776" @default.
- W1982484776 workType "article" @default.