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- W1982484988 abstract "The dynamics of poly(dimethylsiloxane) in its inclusion compound with γ-cyclodextrin are elucidated using modern fast-MAS solid-state NMR techniques. Measurements of methyl 1H–1H and 1H–13C dipolar coupling constants indicate that the polymer undergoes a uniform motion, rendering all methyl groups equivalent. The dynamics of the Si—C bond is characterized by either a dynamic order parameter of S = 0.72, or, assuming a stably rotating helical structure, an inclination angle of 73° relative to the rotation axis." @default.
- W1982484988 created "2016-06-24" @default.
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- W1982484988 date "2002-03-01" @default.
- W1982484988 modified "2023-10-18" @default.
- W1982484988 title "An Investigation of Poly(dimethylsiloxane) Chain Dynamics and Order in Its Inclusion Compound withγ-Cyclodextrin by Fast-MAS Solid-State NMR Spectroscopy" @default.
- W1982484988 doi "https://doi.org/10.1002/1521-3927(20020301)23:4<286::aid-marc286>3.0.co;2-u" @default.
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