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• W1982555277 abstract "Reactions of phenyl radicals were studied in reflected shock waves in the temperature range 1050–1450 K using UV absorption spectroscopy. Rate constants for the following reactions were derived: 2 C6H5→ C12H10 (k1=5.7×1012 cm3 mol−1 s−1), C6H5+H2→C6H6+H (k3=1012.6 exp(−33 kJ mol−1/RT) cm3 mol−1s−1): C6H5+C6H5CH3→C6H6+C6H5CH2 (k4=1013.9 exp(−50 kJ mol−1/RT) cm3 mol−1 s−1), C6H5+CH4→C6H6+CH3 (k5=1012.3 exp(−36 kJ mol−1/RT) cm3 mol−1 s−1), and C6H5+C2H2→C6H5C2H+H (k8=1013.0 exp(−32 kJ mol−1/RT) cm3 mol−1 s−1). Phenyl iodide dissociation equilibrium was also investigated. In combination with results from other laboratories, equilibrium constants for five different equilibria involving phenyl radicals were determined. A third-law analysis of these data leads to an enthalpy of formation of phenyl radicals of ΔHf 298o=(338±3) kJ mol−1." @default.
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• W1982555277 date "1996-01-01" @default.
• W1982555277 modified "2023-09-27" @default.
• W1982555277 title "High-temperature reactions and thermodynamic properties of phenyl radicals" @default.
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• W1982555277 doi "https://doi.org/10.1016/s0082-0784(96)80258-x" @default.
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