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- W1982586034 abstract "We applied the surface complexation model to describe the deprotonation of silica nanochannel walls as a function of pH and ionic strength of filling solution. We took into account energetic heterogeneity of silanol groups. We found that more heterogeneous walls of silica nanochannel will be more charged and can interact more strongly with ionic solutes. The modeling of nanochannels coated with 3-cyanopropydimethylchlorosilane is uncertain because charging mechanism of coated silica should take into account increased autolysis of interfacial water." @default.
- W1982586034 created "2016-06-24" @default.
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- W1982586034 date "2013-02-09" @default.
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- W1982586034 title "The influence of energetic surface heterogeneity on proton desorption during capillary filling of silica nanochannels" @default.
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- W1982586034 doi "https://doi.org/10.1007/s10450-013-9488-5" @default.
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