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- W1982589086 abstract "The titanocene-catalyzed construction of all-carbon substituted tertiary centers directly from aromatic aldehydes is described. The starting aldehyde behaves as a traceless functionality in the formation of multiple carbon–carbon bonds through consecutive carbon–heteroatom bond activations. The sequential addition of a metal acetylide and a second carbon nucleophile to the dielectrophilic aldehyde enables the construction of symmetrical and unsymmetrical 1,4-diynes in good yields." @default.
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- W1982589086 date "2011-09-29" @default.
- W1982589086 modified "2023-09-25" @default.
- W1982589086 title "Aryl Aldehydes as Traceless Dielectrophiles in Bifunctional Titanocene-Catalyzed Propargylic C–X Activations" @default.
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- W1982589086 doi "https://doi.org/10.1021/ol202401n" @default.
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