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- W1982602880 abstract "The isomerization of diterpene epoxides on active neutral alumina has established the existence of new rearrangements of the diterpene skeleton. Methyl 8,14β-epoxysandarcopimarate leads to bicyclic diterpene compounds by a Grob fragmentation, to derivatives of cleistanthane by a 1,2 migration of the vinyl substituent, as well as to one cycloditerpene compound. The 7,8 (or 8,9) derivatives of methyl isopimarate lead essentially to hydroxyolefins formed by a bifunctional acid–base mechanism at the alumina surface. [Journal translation]" @default.
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- W1982602880 date "1988-07-01" @default.
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- W1982602880 title "Obtention de nouveaux squelettes diterpéniques lors de l'isomérisation d'époxydes diterpéniques sur alumine active" @default.
- W1982602880 doi "https://doi.org/10.1139/v88-253" @default.
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