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• W1982670342 startingPage "1473" @default.
• W1982670342 abstract "The terphenyl structure has been proven to be an ideal scaffold mimicking side-chain functionalities of peptidic α-helices. The synthesis of 1,4-dipiperazino benzenes, using stepwise transition metal-catalyzed N-arylation of chiral piperazines to a central benzene core is reported. The structure determination by X-ray crystallography reveals a geometrical arrangement of the hydrophobic side chains resembling the orientation of key i, i + 3, and i + 7 positions in a peptidic α-helix or in terphenyl helix mimetics." @default.
• W1982670342 created "2016-06-24" @default.
• W1982670342 creator A5017529451 @default.
• W1982670342 creator A5067475475 @default.
• W1982670342 date "2008-03-12" @default.
• W1982670342 modified "2023-10-15" @default.
• W1982670342 title "Synthesis and Structure of 1,4-Dipiperazino Benzenes: Chiral Terphenyl-type Peptide Helix Mimetics" @default.
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• W1982670342 doi "https://doi.org/10.1021/ol8002749" @default.
• W1982670342 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/18335950" @default.
• W1982670342 hasPublicationYear "2008" @default.
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