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• W1982676721 abstract "A novel design for a temperature-controlled ICR cell is described for use in black-body infrared radiative dissociation (BIRD) studies of weakly bound systems like water clusters. Due to several improved design features, it provides a very uniform black-body radiation environment, and at the same time maintains efficient pumping for a low collision rate on the order of 10−2 s−1. At the lowest temperatures reached, nominally 89 K cell plate temperature, water evaporation effectively ceases, while intracluster reactions in V+(H2O)n with a small activation energy are still observed. BIRD rate constants for Ag+(H2O)n, n = 4–6, are shown in the temperature range T = 160–320 K. For n = 6, a linear Arrhenius plot with R2 = 0.9943 is obtained without any calibration, confirming the suitability of the cell for quantitative BIRD studies." @default.
• W1982676721 created "2016-06-24" @default.
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• W1982676721 date "2009-01-01" @default.
• W1982676721 modified "2023-10-12" @default.
• W1982676721 title "A novel design of a temperature-controlled FT-ICR cell for low-temperature black-body infrared radiative dissociation (BIRD) studies of hydrated ions" @default.
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• W1982676721 doi "https://doi.org/10.1016/j.ijms.2008.09.001" @default.
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