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- W1982711604 abstract "αZn2P2O7 is a hexpartite structure with a unit cell three times as long in the α direction and twice as long in the c direction as that of the parent βZn2P2O7. The crystal crystallizes with monoclinic symmetry with unit cell parameters of a = 20.068(15)Å, b = 8.259(6)Å, c = 9.099(8)Å and β = 106.35(5)°, Z = 12 and the space group is I2/c. A total of 1841 reflections out of a total of 3740 considered had intensities strong enough to be measured. The structure was refined by full matrix least squares in both the possible space groups Ic and I2/c. The final reliability index is 0.080 for all the data. The coordination number of the cations to oxygen atoms are either 5 (for 2 Zn) or 6 (for 1 Zn) as compared to 6 for all cations in the β phase. All the anions shown nonlinear POP bonds whereas in the β phase they appear linear because of disorder. The two independent anions have POP angles of 139° and 148°. The average inner PO bond length is 1.60 Å while the terminal bond average to 1.52 Å. The average error in the individual PO bond lengths is 0.008 Å. This structure can be characterized as composed of sequences of layers. A layer like that found in αCu2P2O7 is followed by two layers like those found in αMg2P2O7. The former layer has anions lying on two-fold axes and the cations are coordinated to five oxygen atoms while in the next two layers half of the cations are five coordinate while the anions in these layers show only approximate two-fold axes." @default.
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- W1982711604 title "Crystal structure of αZn2P2O7" @default.
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- W1982711604 doi "https://doi.org/10.1016/0022-4596(70)90002-2" @default.
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