FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W1982745923> ?p ?o ?g. }

• W1982745923 endingPage "1440" @default.
• W1982745923 startingPage "1426" @default.
• W1982745923 abstract "Two classes (type A and type B) of novel photolabile divinyl functionalized crosslinkers based on o-nitrobenzyl derivatives were synthesized and investigated with regard to their photolytic performance upon UV irradiation. The systematic variation of the molecular structure resulted in different degradation rates depending on the irradiation conditions. Thus, the successive and independent cleavage is enabled by either adjusting the applied wavelengths or irradiation times. The respective molecules were used to build up photodegradable PMMA microgels by free radical copolymerization with MMA in a miniemulsion polymerization process. UV light-induced degradation of the swollen microgels was monitored by time dependent turbidity measurements and the resulting kinetics were found to correlate with the photolysis rates of the respective crosslinkers in solution. The irradiation wavelength-controlled selective partial cleavage of type B crosslinking points was achieved by UV irradiation with λ > 315 nm and resulted in particles with extensively increased volumes consisting of highly swollen networks. In addition, the irradiation time-controlled selective complete degradation of particles containing type B crosslinkers was accomplished. By using broadband UV light containing wavelengths of λ < 315 nm, the successive complete particle disintegration of type B and type A microgels was observed. Hence, the specific performance of the synthesized microgels can be precisely triggered by means of the used UV light wavelengths, doses and intensities, thus representing a great potential as new light-responsive nanoscaled materials." @default.
• W1982745923 created "2016-06-24" @default.
• W1982745923 creator A5007323274 @default.
• W1982745923 creator A5034838011 @default.
• W1982745923 date "2011-01-01" @default.
• W1982745923 modified "2023-10-01" @default.
• W1982745923 title "Photo-sensitive PMMA microgels: light-triggered swelling and degradation" @default.
• W1982745923 cites W1968545431 @default.
• W1982745923 cites W1968685749 @default.
• W1982745923 cites W1986883628 @default.
• W1982745923 cites W1990521738 @default.
• W1982745923 cites W1992828788 @default.
• W1982745923 cites W1993666713 @default.
• W1982745923 cites W1994399748 @default.
• W1982745923 cites W1995622462 @default.
• W1982745923 cites W1995795656 @default.
• W1982745923 cites W1996173073 @default.
• W1982745923 cites W1999802715 @default.
• W1982745923 cites W2002924086 @default.
• W1982745923 cites W2011345298 @default.
• W1982745923 cites W2013880765 @default.
• W1982745923 cites W2014914514 @default.
• W1982745923 cites W2027588503 @default.
• W1982745923 cites W2029566454 @default.
• W1982745923 cites W2031054981 @default.
• W1982745923 cites W2033899980 @default.
• W1982745923 cites W2034103850 @default.
• W1982745923 cites W2041448801 @default.
• W1982745923 cites W2041780028 @default.
• W1982745923 cites W2045917539 @default.
• W1982745923 cites W2048615711 @default.
• W1982745923 cites W2051809171 @default.
• W1982745923 cites W2057068506 @default.
• W1982745923 cites W2065461682 @default.
• W1982745923 cites W2067897176 @default.
• W1982745923 cites W2069627788 @default.
• W1982745923 cites W2071603269 @default.
• W1982745923 cites W2081817375 @default.
• W1982745923 cites W2089449625 @default.
• W1982745923 cites W2091552691 @default.
• W1982745923 cites W2096884836 @default.
• W1982745923 cites W2100579387 @default.
• W1982745923 cites W2113959224 @default.
• W1982745923 cites W2122328913 @default.
• W1982745923 cites W2124256332 @default.
• W1982745923 cites W2133062319 @default.
• W1982745923 cites W2135490318 @default.
• W1982745923 cites W2137801938 @default.
• W1982745923 cites W2143137409 @default.
• W1982745923 cites W2145496621 @default.
• W1982745923 cites W2145556858 @default.
• W1982745923 cites W2148247140 @default.
• W1982745923 cites W2157901539 @default.
• W1982745923 cites W2168259438 @default.
• W1982745923 cites W230690049 @default.
• W1982745923 cites W2950387069 @default.
• W1982745923 cites W2952662727 @default.
• W1982745923 cites W4242178372 @default.
• W1982745923 doi "https://doi.org/10.1039/c0sm00638f" @default.
• W1982745923 hasPublicationYear "2011" @default.
• W1982745923 type Work @default.
• W1982745923 sameAs 1982745923 @default.
• W1982745923 citedByCount "78" @default.
• W1982745923 countsByYear W19827459232012 @default.
• W1982745923 countsByYear W19827459232013 @default.
• W1982745923 countsByYear W19827459232014 @default.
• W1982745923 countsByYear W19827459232015 @default.
• W1982745923 countsByYear W19827459232016 @default.
• W1982745923 countsByYear W19827459232017 @default.
• W1982745923 countsByYear W19827459232018 @default.
• W1982745923 countsByYear W19827459232019 @default.
• W1982745923 countsByYear W19827459232020 @default.
• W1982745923 countsByYear W19827459232021 @default.
• W1982745923 countsByYear W19827459232022 @default.
• W1982745923 countsByYear W19827459232023 @default.
• W1982745923 crossrefType "journal-article" @default.
• W1982745923 hasAuthorship W1982745923A5007323274 @default.
• W1982745923 hasAuthorship W1982745923A5034838011 @default.
• W1982745923 hasConcept C111337013 @default.
• W1982745923 hasConcept C121332964 @default.
• W1982745923 hasConcept C127413603 @default.
• W1982745923 hasConcept C148898269 @default.
• W1982745923 hasConcept C15920480 @default.
• W1982745923 hasConcept C159985019 @default.
• W1982745923 hasConcept C175156509 @default.
• W1982745923 hasConcept C185544564 @default.
• W1982745923 hasConcept C185592680 @default.
• W1982745923 hasConcept C188027245 @default.
• W1982745923 hasConcept C192562407 @default.
• W1982745923 hasConcept C2776024560 @default.
• W1982745923 hasConcept C2778540859 @default.
• W1982745923 hasConcept C2779679103 @default.
• W1982745923 hasConcept C41008148 @default.
• W1982745923 hasConcept C42360764 @default.
• W1982745923 hasConcept C43369102 @default.
• W1982745923 hasConcept C44228677 @default.
• W1982745923 hasConcept C521977710 @default.
• W1982745923 hasConcept C54582936 @default.

• next