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- W1982748009 abstract "Abstract The heat capacity of [Fe(2-pic)3]Cl2·C2H5OH Crystal (2-pic: 2-picolylamine) has been measured with an adiabatic calorimeter between 13 and 315 K. Two phase transitions centered at 114.04 and 122.21 K were observed. This finding accords with recent prediction of possible existence of two-step spin-conversion (H. Koppen et al., Chem. Phys. Lett., 91 (1982) 348). The total transition enthalpy and entropy amounted to ΔH = 6.14 kJ mol−1 and ΔS = 50.59 J K−1 mol−1. The transition entropy consists of the magnetic contribution (13.38 J K−1 mol−1), the orientational order-disorder phenomenon of the solvate ethanol molecule (8.97) and the change in the phonon system, in particular the change in stretching and deformation vibrations of the metal-ligand (28.24)." @default.
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- W1982748009 date "1985-06-01" @default.
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- W1982748009 title "Heat capacity and dual spin-transitions in the crossover system [Fe(2-pic)3]Cl2·EtOH" @default.
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- W1982748009 doi "https://doi.org/10.1016/0040-6031(85)85426-5" @default.
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