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• W1982753801 endingPage "850" @default.
• W1982753801 startingPage "838" @default.
• W1982753801 abstract "The design and fabrication of catalytic materials is a key issue in heterogeneous catalysis to achieve desired performance. Traditionally, the main theme is to reduce the size of the catalyst particles as small as possible for increasing the number of active sites. In recent years, the rapid advancement in materials science has enabled us to fabricate catalyst particles with tunable shape at nanometer level. Through morphology control of nanoparticles by exposing highly reactive crystal planes, their catalytic properties can be drastically enhanced. Therefore, both size modulation and shape control of catalyst nanoparticles can be achieved independently or synergistically to optimize their catalytic behavior. We highlight, in this review, the recent progress in shape control of CeO 2 materials that are widely used as crucial components or structural and electronic promoters in heterogeneous catalysts. We first summarize the major synthetic strategies and characteristics of shape-controlled CeO 2 nanomaterials. We then survey morphology-dependent nanocatalysis of CeO 2 and Au-CeO 2 catalysts. We understand now that the enhanced catalytic property of the Au-CeO 2 system is closely related to the unique interaction between the gold nanoparticles and the ceria support; such an interaction originates from the particular shape of ceria, especially the exposed facets. Finally, we present our understanding of the morphology-dependent nanocatalysis and provide our perspectives on their future potential and development. The fundamental understanding of the nature of the intrinsic active sites of the shape-tunable ceria nanostructures, enclosed by reactive crystal planes/facets with unique properties, is expected to provide highly efficient nanocatalysts for practical applications. 催化剂的设计、合成和结构调控是获得优异性能的关键. 传统的策略主要是尽量减小催化剂颗粒尺寸以增加活性中心的数目, 即尺寸效应. 近年来, 材料科学的快速发展使得在纳米尺度上调变催化剂的尺寸和形貌成为可能, 特别是通过形貌调控可暴露更多的高活性晶面, 大幅度提高催化性能, 即纳米催化中的形貌效应. 因此, 调节催化剂的尺寸与形貌可以单独或协同优化材料的性能. 氧化铈作为催化剂的重要组分与结构、电子促进剂被广泛应用于多相催化剂体系. 本文总结了近期氧化铈材料形貌可控合成的进展, 包括主要的合成策略和表征方法; 进而分析了氧化铈和金-氧化铈催化材料的形貌效应, 指出金-氧化铈之间独特的相互作用与载体形貌密切相关; 阐述了氧化铈纳米材料因暴露晶面的差异而获得不同催化性能的化学机制. The catalytic performance of CeO 2 materials can be adjusted via tuning their shape at nanometer level by exposing different crystal planes, which influences both reaction pathway and metal-support interaction." @default.
• W1982753801 created "2016-06-24" @default.
• W1982753801 creator A5016825655 @default.
• W1982753801 creator A5019146446 @default.
• W1982753801 creator A5048881523 @default.
• W1982753801 date "2013-05-01" @default.
• W1982753801 modified "2023-09-26" @default.
• W1982753801 title "Tuning the shape of ceria nanomaterials for catalytic applications" @default.
• W1982753801 cites W1512034926 @default.
• W1982753801 cites W1581420010 @default.
• W1982753801 cites W1963920922 @default.
• W1982753801 cites W1965908212 @default.
• W1982753801 cites W1966161952 @default.
• W1982753801 cites W1966548426 @default.
• W1982753801 cites W1973953565 @default.
• W1982753801 cites W1975446894 @default.
• W1982753801 cites W1975643895 @default.
• W1982753801 cites W1977241440 @default.
• W1982753801 cites W1979739611 @default.
• W1982753801 cites W1981792803 @default.
• W1982753801 cites W1982943286 @default.
• W1982753801 cites W1983446535 @default.
• W1982753801 cites W1985059073 @default.
• W1982753801 cites W1986116875 @default.
• W1982753801 cites W1986666150 @default.
• W1982753801 cites W1986712264 @default.
• W1982753801 cites W1992895793 @default.
• W1982753801 cites W1993627986 @default.
• W1982753801 cites W1994859229 @default.
• W1982753801 cites W1995379479 @default.
• W1982753801 cites W1996507681 @default.
• W1982753801 cites W1997969032 @default.
• W1982753801 cites W1998530139 @default.
• W1982753801 cites W1999184945 @default.
• W1982753801 cites W1999191448 @default.
• W1982753801 cites W2002427705 @default.
• W1982753801 cites W2003226529 @default.
• W1982753801 cites W2004249211 @default.
• W1982753801 cites W2005448605 @default.
• W1982753801 cites W2006680220 @default.
• W1982753801 cites W2008799217 @default.
• W1982753801 cites W2008975790 @default.
• W1982753801 cites W2009110629 @default.
• W1982753801 cites W2012583945 @default.
• W1982753801 cites W2014907980 @default.
• W1982753801 cites W2016779481 @default.
• W1982753801 cites W2020275278 @default.
• W1982753801 cites W2020514358 @default.
• W1982753801 cites W2022190942 @default.
• W1982753801 cites W2023322304 @default.
• W1982753801 cites W2023732692 @default.
• W1982753801 cites W2025618112 @default.
• W1982753801 cites W2027969018 @default.
• W1982753801 cites W2030215265 @default.
• W1982753801 cites W2032395488 @default.
• W1982753801 cites W2034496824 @default.
• W1982753801 cites W2034853155 @default.
• W1982753801 cites W2035364133 @default.
• W1982753801 cites W2037209735 @default.
• W1982753801 cites W2040696064 @default.
• W1982753801 cites W2040707378 @default.
• W1982753801 cites W2041170068 @default.
• W1982753801 cites W2042418262 @default.
• W1982753801 cites W2042894753 @default.
• W1982753801 cites W2043494536 @default.
• W1982753801 cites W2043577611 @default.
• W1982753801 cites W2044842642 @default.
• W1982753801 cites W2046849974 @default.
• W1982753801 cites W2047240993 @default.
• W1982753801 cites W2047849169 @default.
• W1982753801 cites W2048255466 @default.
• W1982753801 cites W2053268170 @default.
• W1982753801 cites W2054137981 @default.
• W1982753801 cites W2055421799 @default.
• W1982753801 cites W2058115665 @default.
• W1982753801 cites W2059190423 @default.
• W1982753801 cites W2060509766 @default.
• W1982753801 cites W2061207822 @default.
• W1982753801 cites W2061820211 @default.
• W1982753801 cites W2067031999 @default.
• W1982753801 cites W2067077957 @default.
• W1982753801 cites W2067642063 @default.
• W1982753801 cites W2069483642 @default.
• W1982753801 cites W2070247802 @default.
• W1982753801 cites W2070815718 @default.
• W1982753801 cites W2072249730 @default.
• W1982753801 cites W2074928268 @default.
• W1982753801 cites W2075065034 @default.
• W1982753801 cites W2076260321 @default.
• W1982753801 cites W2077667363 @default.
• W1982753801 cites W2078968560 @default.
• W1982753801 cites W2081292041 @default.
• W1982753801 cites W2081561096 @default.
• W1982753801 cites W2082279765 @default.
• W1982753801 cites W2083133363 @default.
• W1982753801 cites W2084787818 @default.
• W1982753801 cites W2085963339 @default.
• W1982753801 cites W2087617618 @default.

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