FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W1982754041> ?p ?o ?g. }

• W1982754041 endingPage "L423" @default.
• W1982754041 startingPage "L417" @default.
• W1982754041 abstract "Electron magnetic resonance (EMR) studies of paramagnetic species with the spin S ⩾ 1 at orthorhombic symmetry sites require an axial zero-field splitting (ZFS) parameter and a rhombic one of the second order (k = 2), whereas at triclinic sites all five ZFS (k = 2) parameters are expressed in the crystallographic axis system. For the spin S ⩾ 2 also the higher-order ZFS terms must be considered. In the principal axis system, instead of the five ZFS (k = 2) parameters, the two principal ZFS values can be used, as for orthorhombic symmetry; however, then the orientation of the principal axes with respect to the crystallographic axis system must be provided. Recently three serious cases of incorrect relations between the extended Stevens ZFS parameters and the conventional ones have been identified in the literature. The first case concerns a controversy concerning the second-order rhombic ZFS parameters and was found to have lead to misinterpretation, in a review article, of several values of either E or b22 published earlier. The second case concerns the set of five relations between the extended Stevens ZFS parameters bkq and the conventional ones Dij for triclinic symmetry, four of which turn out to be incorrect. The third case concerns the omission of the scaling factors fk for the extended Stevens ZFS parameters bkq. In all cases the incorrect relations in question have been published in spite of the earlier existence of the correct relations in the literature. The incorrect relations are likely to lead to further misinterpretation of the published values of the ZFS parameters for orthorhombic and lower symmetry. The purpose of this paper is to make the spectroscopists working in the area of EMR (including EPR and ESR) and related spectroscopies aware of the problem and to reduce proliferation of the incorrect relations." @default.
• W1982754041 created "2016-06-24" @default.
• W1982754041 creator A5076452276 @default.
• W1982754041 date "2000-06-07" @default.
• W1982754041 modified "2023-10-12" @default.
• W1982754041 title "On the relations between the zero-field splitting parameters in the extended Stevens operator notation and the conventional ones used in EMR for orthorhombic and lower symmetry" @default.
• W1982754041 cites W125654249 @default.
• W1982754041 cites W1645647506 @default.
• W1982754041 cites W1965927183 @default.
• W1982754041 cites W1966499336 @default.
• W1982754041 cites W1968769605 @default.
• W1982754041 cites W1979712899 @default.
• W1982754041 cites W1982459596 @default.
• W1982754041 cites W1984355917 @default.
• W1982754041 cites W1996206251 @default.
• W1982754041 cites W2011494680 @default.
• W1982754041 cites W2012297088 @default.
• W1982754041 cites W2034111652 @default.
• W1982754041 cites W2035976010 @default.
• W1982754041 cites W2052738531 @default.
• W1982754041 cites W2056042616 @default.
• W1982754041 cites W2059897107 @default.
• W1982754041 cites W2067727518 @default.
• W1982754041 cites W2074299299 @default.
• W1982754041 cites W2142154334 @default.
• W1982754041 cites W3032438804 @default.
• W1982754041 cites W3198245712 @default.
• W1982754041 doi "https://doi.org/10.1088/0953-8984/12/25/106" @default.
• W1982754041 hasPublicationYear "2000" @default.
• W1982754041 type Work @default.
• W1982754041 sameAs 1982754041 @default.
• W1982754041 citedByCount "44" @default.
• W1982754041 countsByYear W19827540412012 @default.
• W1982754041 countsByYear W19827540412013 @default.
• W1982754041 countsByYear W19827540412014 @default.
• W1982754041 countsByYear W19827540412015 @default.
• W1982754041 countsByYear W19827540412018 @default.
• W1982754041 countsByYear W19827540412019 @default.
• W1982754041 countsByYear W19827540412021 @default.
• W1982754041 crossrefType "journal-article" @default.
• W1982754041 hasAuthorship W1982754041A5076452276 @default.
• W1982754041 hasConcept C10138342 @default.
• W1982754041 hasConcept C115624301 @default.
• W1982754041 hasConcept C121332964 @default.
• W1982754041 hasConcept C147120987 @default.
• W1982754041 hasConcept C161326058 @default.
• W1982754041 hasConcept C162324750 @default.
• W1982754041 hasConcept C182306322 @default.
• W1982754041 hasConcept C185592680 @default.
• W1982754041 hasConcept C202444582 @default.
• W1982754041 hasConcept C21690051 @default.
• W1982754041 hasConcept C2524010 @default.
• W1982754041 hasConcept C26873012 @default.
• W1982754041 hasConcept C2779886137 @default.
• W1982754041 hasConcept C33923547 @default.
• W1982754041 hasConcept C37243968 @default.
• W1982754041 hasConcept C40567970 @default.
• W1982754041 hasConcept C42228675 @default.
• W1982754041 hasConcept C62520636 @default.
• W1982754041 hasConcept C8010536 @default.
• W1982754041 hasConcept C9652623 @default.
• W1982754041 hasConceptScore W1982754041C10138342 @default.
• W1982754041 hasConceptScore W1982754041C115624301 @default.
• W1982754041 hasConceptScore W1982754041C121332964 @default.
• W1982754041 hasConceptScore W1982754041C147120987 @default.
• W1982754041 hasConceptScore W1982754041C161326058 @default.
• W1982754041 hasConceptScore W1982754041C162324750 @default.
• W1982754041 hasConceptScore W1982754041C182306322 @default.
• W1982754041 hasConceptScore W1982754041C185592680 @default.
• W1982754041 hasConceptScore W1982754041C202444582 @default.
• W1982754041 hasConceptScore W1982754041C21690051 @default.
• W1982754041 hasConceptScore W1982754041C2524010 @default.
• W1982754041 hasConceptScore W1982754041C26873012 @default.
• W1982754041 hasConceptScore W1982754041C2779886137 @default.
• W1982754041 hasConceptScore W1982754041C33923547 @default.
• W1982754041 hasConceptScore W1982754041C37243968 @default.
• W1982754041 hasConceptScore W1982754041C40567970 @default.
• W1982754041 hasConceptScore W1982754041C42228675 @default.
• W1982754041 hasConceptScore W1982754041C62520636 @default.
• W1982754041 hasConceptScore W1982754041C8010536 @default.
• W1982754041 hasConceptScore W1982754041C9652623 @default.
• W1982754041 hasIssue "25" @default.
• W1982754041 hasLocation W19827540411 @default.
• W1982754041 hasOpenAccess W1982754041 @default.
• W1982754041 hasPrimaryLocation W19827540411 @default.
• W1982754041 hasRelatedWork W1990517428 @default.
• W1982754041 hasRelatedWork W1997824979 @default.
• W1982754041 hasRelatedWork W2033857906 @default.
• W1982754041 hasRelatedWork W2050815233 @default.
• W1982754041 hasRelatedWork W2087318248 @default.
• W1982754041 hasRelatedWork W2125768859 @default.
• W1982754041 hasRelatedWork W2171713381 @default.
• W1982754041 hasRelatedWork W2356845202 @default.
• W1982754041 hasRelatedWork W2357600621 @default.
• W1982754041 hasRelatedWork W4200547711 @default.
• W1982754041 hasVolume "12" @default.
• W1982754041 isParatext "false" @default.
• W1982754041 isRetracted "false" @default.

• next