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- W1982794995 endingPage "1947" @default.
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- W1982794995 abstract "Evidence has been presented for the transient formation of a dienone-imine intermediate in the Fischer indole synthesis analogous to the dienone intermediate found in the Claisen rearrangement. The isolation of methylamine hydrochloride, 8-chloro-1,2,3,4-tetrahydrocarbazole, and 5-amino-6-chloro-9-methyl-1,2,3,4-tetrahydrocarbazole from the room temperature, uncatalyzed condensation between cyclohexanone and N′-methyl-2,6-dichlorophenylhydrazine under enamine synthesis conditions can be rationalized only on the assumption of the occurrence of a dienone-imine intermediate. An example of a facile, uncatalyzed Fischer cyclization at room temperature has been described." @default.
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- W1982794995 date "1964-08-01" @default.
- W1982794995 modified "2023-09-26" @default.
- W1982794995 title "FURTHER EVIDENCE FOR THE DIENONE-IMINE INTERMEDIATE IN THE FISCHER INDOLE SYNTHESIS: AN UNCATALYZED FISCHER REACTION UNDER MILD CONDITIONS" @default.
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- W1982794995 doi "https://doi.org/10.1139/v64-287" @default.
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