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• W1982858378 abstract "Many of the individual steps which make up the reaction of carbon and water to produce CO and H2 were studied on a nickel foil surface using temperature-programmed reaction spectroscopy (TPRS), Auger electron spectroscopy (AES), and ultraviolet photoelectron spectroscopy (UPS). Surface graphite and carbide, two metastable surface carbon forms, were prepared by dehydrogeneration of C2H2 and served as reactant carbon. UPS of the graphite monolayer in contact with the metal yielded a valence electronic structure that could be interpreted in terms of the bulk band structure of graphite. The fully carbided Ni surface was active for H2O dissociation with an estimated activation energy ≤ 5 kcal/mol. The reaction of graphitic carbon in contact with the nickel surface and adsorbed oxygen occurs directly without isolated prior breaking of carbon-carbon bonds. The estimated activation energy for the direct reaction was 44 kcal/mol. A different catalytic reaction cycle involving carbon-carbon bond breaking followed by oxidation of the carbide is energetically more demanding. The activation energy for direct carbon-carbon bond breaking was estimated to be between 65 and 70 kcal/mol. Following this demanding step, the reaction between carbidic carbon and oxygen proceeded with estimated activation energy of 31 kcal/mol." @default.
• W1982858378 created "2016-06-24" @default.
• W1982858378 creator A5059299554 @default.
• W1982858378 date "1987-07-01" @default.
• W1982858378 modified "2023-10-17" @default.
• W1982858378 title "The reaction of carbon and water as catalyzed by a nickel surface" @default.
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• W1982858378 cites W1600219414 @default.
• W1982858378 cites W184048685 @default.
• W1982858378 cites W1966049922 @default.
• W1982858378 cites W1967648258 @default.
• W1982858378 cites W1968008235 @default.
• W1982858378 cites W1972292196 @default.
• W1982858378 cites W1972614027 @default.
• W1982858378 cites W1973833871 @default.
• W1982858378 cites W1976045479 @default.
• W1982858378 cites W1977154669 @default.
• W1982858378 cites W1978483352 @default.
• W1982858378 cites W1978856174 @default.
• W1982858378 cites W1979343624 @default.
• W1982858378 cites W1979756930 @default.
• W1982858378 cites W1979996029 @default.
• W1982858378 cites W1983346053 @default.
• W1982858378 cites W1983520208 @default.
• W1982858378 cites W1986269719 @default.
• W1982858378 cites W1989994250 @default.
• W1982858378 cites W1994834854 @default.
• W1982858378 cites W1999618353 @default.
• W1982858378 cites W2000991326 @default.
• W1982858378 cites W2004080468 @default.
• W1982858378 cites W2004968304 @default.
• W1982858378 cites W2005709830 @default.
• W1982858378 cites W2005722017 @default.
• W1982858378 cites W2006069907 @default.
• W1982858378 cites W2006595754 @default.
• W1982858378 cites W2011171456 @default.
• W1982858378 cites W2012014084 @default.
• W1982858378 cites W2012536320 @default.
• W1982858378 cites W2013153134 @default.
• W1982858378 cites W2013435963 @default.
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• W1982858378 cites W2018761181 @default.
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• W1982858378 cites W2025219452 @default.
• W1982858378 cites W2026331749 @default.
• W1982858378 cites W2028250529 @default.
• W1982858378 cites W2029396898 @default.
• W1982858378 cites W2030445021 @default.
• W1982858378 cites W2032448199 @default.
• W1982858378 cites W2032522208 @default.
• W1982858378 cites W2032759411 @default.
• W1982858378 cites W2035013186 @default.
• W1982858378 cites W2035808271 @default.
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• W1982858378 cites W2041035467 @default.
• W1982858378 cites W2043255274 @default.
• W1982858378 cites W2043281734 @default.
• W1982858378 cites W2046515069 @default.
• W1982858378 cites W2052015885 @default.
• W1982858378 cites W2054543470 @default.
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• W1982858378 cites W2058787784 @default.
• W1982858378 cites W2058806817 @default.
• W1982858378 cites W2066683734 @default.
• W1982858378 cites W2071434975 @default.
• W1982858378 cites W2075577729 @default.
• W1982858378 cites W2077959125 @default.
• W1982858378 cites W2079104613 @default.
• W1982858378 cites W2079588104 @default.
• W1982858378 cites W2080338265 @default.
• W1982858378 cites W2081203374 @default.
• W1982858378 cites W2084019983 @default.
• W1982858378 cites W2088974490 @default.
• W1982858378 cites W2097067717 @default.
• W1982858378 cites W2117841517 @default.
• W1982858378 cites W2150941316 @default.
• W1982858378 cites W2481440761 @default.
• W1982858378 cites W2512242068 @default.
• W1982858378 cites W3023017275 @default.
• W1982858378 cites W4231971174 @default.
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• W1982858378 doi "https://doi.org/10.1016/0169-4332(87)90142-5" @default.
• W1982858378 hasPublicationYear "1987" @default.
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