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- W1982870279 endingPage "140" @default.
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- W1982870279 abstract "The DISQUAC group contribution model has been applied to the study of mixtures containing a polycyclic aromatic compound, naphthalene, phenanthrene, anthracene or pyrene, and an organic solvent, n-alkane, cyclohexane or 1-alkanol. The corresponding interaction parameters are reported. Systems with alkanes are characterized by dispersive parameters only. For naphthalene + 1-alkanol mixtures, the aromatic/OH contacts are represented by dispersive and quasichemical parameters. The latter are equal to those encountered in 1-alkanol + benzene, or + alkylbenzene mixtures for such contacts. DISQUAC provides good results on molar excess enthalpies, HE, solid–liquid equilibria, SLE, and vapor–liquid equilibria over a wide range of temperature for the investigated mixtures. In PAH + n-alkane systems, there is an enthalpy-entropy compensation effect in solutions with long alkanes, and no Patterson's effect is observed. Solubility of naphthalene in hexane or 1-hexanol is similar, and lower than that of 1-alkanol in alkane. This seems to indicate that interactions between unlike molecules are not so relevant as in 1-alkanol + benzene mixtures." @default.
- W1982870279 created "2016-06-24" @default.
- W1982870279 creator A5017577532 @default.
- W1982870279 creator A5018079994 @default.
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- W1982870279 date "2008-10-01" @default.
- W1982870279 modified "2023-09-27" @default.
- W1982870279 title "Thermodynamics of mixtures containing polycyclic aromatic hydrocarbons" @default.
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- W1982870279 doi "https://doi.org/10.1016/j.molliq.2008.07.005" @default.
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