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• W1982891349 abstract "Relative partial photoionization cross sections have been measured for the valence bands of [(η-C6H6)2Cr] and [(η-C6H5Me)2Mo] over the photon energy ranges 24–80 eV ([(η-C6H6)2Cr]) and 24–100 eV ([(η-C6H5Me)2Mo]). Both compounds show pronounced intensity increases of the metal-based ionizations (a−11g and e−12g) in the region of the np subshell ionization potentials, attribute to nd resonant photoemission following np→nd giant resonant absorption. Shape resonances are also observed in the cross sections of these bands. For [(η-C6H5Me)2Mo], the two resonance processes are almost coincident in photon energy, but can be distinguished more clearly in the [(η-C6H6)2Cr] cross sections. Evidence for metal d—carbon 2pπ covalency in the e1g set of molecular orbitals is found, with features in the cross sections of the metal-based bands correlating with those in the e−11g ionizations. The e−11u bands show an essentially monotonic cross section decrease with photon energy." @default.
• W1982891349 created "2016-06-24" @default.
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• W1982891349 date "1992-08-01" @default.
• W1982891349 modified "2023-10-03" @default.
• W1982891349 title "Electron localization in the bis-arene complexes [(η-C6H6)2Cr] and [(η-C6H5Me)2Mo]: an investigation by photoelectron spectroscopy with variable photon energy" @default.
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• W1982891349 doi "https://doi.org/10.1016/0301-0104(92)87150-8" @default.
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