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• W1982903110 abstract "Abstract NMR study of the reactivity of multifunctional ligand cis,cis -C 6 H 9 (NHCH 2 C 6 H 4 - o -PPh 2 ) 3 ( 1 ) with GaMe 3 and Zr(NMe 2 ) 4 was carried out, yielding [ cis,cis -(κ N -NHCH 2 C 6 H 4 - o -PPh 2 )(κ N -NCH 2 C 6 H 4 - o -PPh 2 ) 2 C 6 H 9 ]GaMe ( 2 ) and [ cis,cis -(NCH 2 C 6 H 4 - o -PPh 2 ) 3 C 6 H 9 ]Ga 2 Me 3 ( 3 ), and [ cis,cis -(NCH 2 C 6 H 4 - o -PPh 2 ) 3 C 6 H 9 ]Zr(NMe 2 ) ( 4 ), respectively. The spectral properties of 2 and 3 are very similar to that observed for the equivalent aluminum species already reported, but form at a much slower rate which allows for the observation of a GaMe 3 ⋅ 1 adduct. Species 4 undergoes coordination/displacement of one of the phosphine arms, which was observed using both NMR spectroscopy and DFT analyses." @default.
• W1982903110 created "2016-06-24" @default.
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• W1982903110 date "2011-05-01" @default.
• W1982903110 modified "2023-09-25" @default.
• W1982903110 title "Reactivity of a functionalized trisamido ligand with Zr(NMe2)4 and GaMe3" @default.
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• W1982903110 doi "https://doi.org/10.1016/j.jorganchem.2010.11.038" @default.
• W1982903110 hasPublicationYear "2011" @default.
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