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- W1982904706 abstract "A new approach to control the supramolecular organization of conjugated polymers is proposed, based on stereocomplex formation. It is illustrated by mixing polymer solutions of block copolymers, i.e., poly(3-hexylthiophene)-b-poly(l-lactide) and poly(3-hexylthiophene)-b-poly(d-lactide). The block copolymers were successfully synthesized via a three-step procedure including the use of metal-free organic catalysts in the ring-opening polymerization of l- and d-lactide. The thermal properties and microscopic morphology of sterecomplexed diblock copolymers show that the stereocomplexation of the polylactide blocks is able to prevent the crystallization of the regioregular poly(3-hexylthiophene) block into long-range ordered parallel fibrillar structures. Stereocomplexation is also observed when mixing poly(d-lactide) homopolymer and poly(3-hexylthiophene)-b-poly(l-lactide) block copolymer." @default.
- W1982904706 created "2016-06-24" @default.
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- W1982904706 date "2010-10-13" @default.
- W1982904706 modified "2023-10-17" @default.
- W1982904706 title "Stereocomplexed Materials Based on Poly(3-hexylthiophene)-<i>b</i>-poly(lactide) Block Copolymers: Synthesis by Organic Catalysis, Thermal Properties, and Microscopic Morphology" @default.
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- W1982904706 doi "https://doi.org/10.1021/ma1012336" @default.
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