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- W1982912691 abstract "Die Rotationsbarriere der CC-Bindungen im 1,3-Dimethyl-(1a) und 1,3-Di-tert-butylallen (1b) wurde aus den in der Gasphase ermittelten Racemisierungsgeschwindigkeiten zu 46.17 bzw. 46.91 kcal/mol bestimmt. Durch Vergleich mit der Rotationsbarriere im 2-Buten ergibt sich für die Resonanzenergie des Allyl-Radikals ein Wert von 14.0 kcal/mol (abgeschätzter Fehler ± 2 kcal/mol). Rotational Barrier in 1,2-Dienes; Resonance Energy of the Allylic Radical From the rate of racemisation of 1,3-dimethyl- (1a) and 1,3-di-tert-butylallene (1b) in the gas phase the rotational barriers of the CC bonds were determined to be 46.17 and 46.91 kcal/mole, respectively. By comparison with the rotational barrier of 2-butene a value of 14.0 kcal/mole is obtained for the resonance energy of the allylic radical (estimated uncertainty ± 2 kcal/mole)." @default.
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- W1982912691 date "1974-01-01" @default.
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- W1982912691 title "Rotationsbarriere in 1,2‐Dienen; Resonanzenergie des Allyl‐Radikals" @default.
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- W1982912691 doi "https://doi.org/10.1002/cber.19741070106" @default.
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