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• W1982913584 startingPage "747" @default.
• W1982913584 abstract "Several new group 13 element compounds containing the 1-[2-(dimethylamino)ethyl]-2,3,4,5-tetramethylcyclopentadienyl ligand (Cp∧) are described. Reaction of the respective element halide with Cp∧Li leads to the compounds 2−8 of the type (C5Me4CH2CH2NMe2)MX2 [2, M = Al, X = CH3; 3, M = Al, X = C2H5; 4, M = Al, X = Cl; 5, M = Al, X = Br; 6, M = Al, X = I; 7, M = Ga, X = Cl; 8, M = In, X = Cl]. All compounds feature monomeric structures with intramolecularly coordinated dimethylamino groups. The dynamic behavior in solution is based on fast haptotropic shifts in a “windscreen-wiper” type process. In the reaction of 5 with H3Al·NMe3, the compound (C5Me4CH2CH2NMe2)Al(H)Br (9) is formed. The known correlation of the 27Al NMR shift with the coordination number at aluminum can be extended to cyclopentadienyl compounds. The structures of 2, 4, and 8 were established by X-ray crystallography." @default.
• W1982913584 created "2016-06-24" @default.
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• W1982913584 date "1996-01-23" @default.
• W1982913584 modified "2023-10-16" @default.
• W1982913584 title "Synthesis and Properties of Group 13 Element Compounds (Al, Ga, In) with the Polydentate 1-[2-(Dimethylamino)ethyl]-2,3,4,5-tetramethylcyclopentadienyl Ligand. X-ray Crystal Structures of (C₅Me₄CH₂CH₂NMe₂)MX₂ (MX₂= AlMe₂, AlCl₂, InCl₂)¹" @default.
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• W1982913584 doi "https://doi.org/10.1021/om9505975" @default.
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