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- W1982920869 abstract "When aqueous solution of aluminium salt involving nitrate, chloride or sulfate was added into sodium fluoride solution, an immediate reaction occured to form cryolite-like precipitate. Examination into the resultant solution and analysis for the precipitate were carried out, leading to the fact that fluorine ion can substitute for bound water molecules around central Al+++ ion, but hardly for bound hydroxide and sulfate ion which should go or be “frozen”, as it is, into cryolite-like precipitate. These ligand substitution reaction seems to contribute to identification of ion species of aluminium in aqueous solution. Bei der Zugabe von Aluminiumnitrat, -chlorid oder -sulfat-Lösungen zu NaF-Lösungen entsteht sofort eine kryolith-ähnliche Fällung. Die Untersuchung der Restlösung und des Niederschlages ergab, daß das F–-Ion am Al+++-Ion gebundene H2O-Molekeln substituieren kann, nicht aber OH–oder SO4 –-Ionen, die infolgedessen in die kryolith-ähnliche Fällung übergehen. Auf Grund der Verhältnisse dieser Liganden-Austauschreaktionen scheint es möglich, die in wäßriger Al-Salz-Lösung vorhandenen Spezies zu indentifizieren." @default.
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- W1982920869 date "1971-12-01" @default.
- W1982920869 modified "2023-09-24" @default.
- W1982920869 title "Cryolite precipitation by the Reaction of aluminium salt with sodium fluoride in aqueous solution" @default.
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- W1982920869 doi "https://doi.org/10.1002/zaac.19713860218" @default.
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